ArticleACS omega2022
Adsorption and Removal of Mercury(II) by a Crosslinked Hyperbranched Polymer Modified via Sulfhydryl.
Article in ACS omega, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 32 citations in OpenAlex.
- Multifunctional electrospun PVDF/CS-Al/Cu-LDH hybrid nanofiber membrane with superior Hg(II) adsorption efficiency and dual anticancer-antioxidant bioactivity.Scientific reports · 2026Article
- Preparation of thiol-functionalized polyurethane foam and its adsorption performance for Hg(ii).RSC advances · 2025Article
- Facile Doping and Functionalization of Molybdic Acid into Nanobiochar to Enhance Mercury Ion Removal from Water Systems.Nanomaterials (Basel, Switzerland) · 2024Article
- Efficient Removal of Mercury from Wastewater Solutions by a Nitrogen-Doped Hyper-Crosslinked Polyamine.Polymers · 2024Article
- Dual-Responsive Hydrogels for Mercury Ion Detection and Removal from Wastewater.Gels (Basel, Switzerland) · 2024Article
- Facilitated Adsorption of Mercury(II) and Chromium(VI) Ions over Functionalized Carbon Nanotubes.Toxics · 2023Article
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In this study, the highly crosslinked hyperbranched polyamide-amines (H-PAMAMs) were first prepared via one-pot methods and then modified with thiourea to synthesize a novel adsorbent containing sulfhydryl groups (CHAP-SH), which was used to adsorb Hg(II) ions from aqueous solutions. The adsorption characteristics and mechanism of CHAP-SH for Hg(II) ions were systematically studied. As expected, CHAP-SH exhibited a rapid removal performance toward Hg(II), and the maximum adsorption capacity was 282.74 mg/g at 318 K and pH = 4.5. The whole adsorption behavior could be well described by the pseudo-second-order kinetic model and Langmuir and Redlich-Peterson adsorption isotherm models, which reflected that the adsorption process was mainly monolayer chemisorption. Meanwhile, CHAP-SH had strong selectivity for Hg(II) in the presence of multimetal ions, and it had excellent recoverability after five cycles. In order to further elucidate the adsorption mechanism, the adsorbents before and after adsorption were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and energy-dispersive X-ray spectroscopy, and the results showed that the nitrogen-containing, oxygen-containing, and sulfur-containing groups in the adsorbent molecule had synergistic complexation with Hg(II). These results indicated that the adsorbents had great potential in the future treatment of aqueous solutions containing Hg(II).
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Registered trials
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