Evidence map›Paper›PMID 35449202›Full record

ArticleNature communications2022

Multivariate analysis of disorder in metal-organic frameworks.

Adam F Sapnik, Irene Bechis, Alice M Bumstead, Timothy Johnson, Philip A Chater, David A Keen, Kim E Jelfs, Thomas D Bennett

Abstract read
In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed.

  1. Manipulating Thermal Transport of 2D MOFs by Hierarchical Structural Design.Small (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  2. Article
  3. Article
  4. Article
  5. Review
  6. Breaking the photoswitch speed limit.Nature communications · 2023
    Article
  7. Article
  8. Article
  9. Article
  10. Review
  11. Modeling the Effect of Defects and Disorder in Amorphous Metal-Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Adam F SapnikDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK.ORCID http://orcid.org/0000-0001-6200-4208
Irene BechisDepartment of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London, W12 0BZ, UK.ORCID http://orcid.org/0000-0001-7322-2446
Alice M BumsteadDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK.ORCID http://orcid.org/0000-0001-9269-1731
Timothy JohnsonJohnson Matthey Technology Centre, Blount's Court, Sonning Common, Reading, RG4 9NH, UK.ORCID http://orcid.org/0000-0003-4651-7374
Philip A ChaterDiamond Light Source Ltd, Diamond House, Harwell Campus, Didcot, Oxfordshire, OX11 0DE, UK.ORCID http://orcid.org/0000-0002-5513-9400
David A KeenISIS Neutron and Muon Facility, Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire, OX11 0QX, UK.ORCID http://orcid.org/0000-0003-0376-2767
Kim E JelfsDepartment of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London, W12 0BZ, UK.ORCID http://orcid.org/0000-0001-7683-7630
Thomas D BennettDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.ORCID http://orcid.org/0000-0003-3717-3119

Funding

EC | EC Seventh Framework Programm | FP7 Ideas: European Research Council (FP7-IDEAS-ERC - Specific Programme: "Ideas" Implementing the Seventh Framework Programme of the European Community for Research, Technological Development and Demonstration Activities (2007 to 2013)) CoMMaD, ERC Grant No. 758370)RCUK | Engineering and Physical Sciences Research Council (EPSRC) JM11106Royal Society UF150021
6 · The paper itself

Abstract

The rational design of disordered frameworks is an appealing route to target functional materials. However, intentional realisation of such materials relies on our ability to readily characterise and quantify structural disorder. Here, we use multivariate analysis of pair distribution functions to fingerprint and quantify the disorder within a series of compositionally identical metal-organic frameworks, possessing different crystalline, disordered, and amorphous structures. We find this approach can provide powerful insight into the kinetics and mechanism of structural collapse that links these materials. Our methodology is also extended to a very different system, namely the melting of a zeolitic imidazolate framework, to demonstrate the potential generality of this approach across many areas of disordered structural chemistry.

Identifiers

PMID35449202
PMCPMC9023516

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.