ArticleAngewandte Chemie (International ed. in English)2022
Mapping Active Site Geometry to Activity in Immobilized Frustrated Lewis Pair Catalysts.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Modular Framework for 3D Molecular Generation in Computational Chemistry Applications.Journal of the American Chemical Society · 2026Article
- Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysis.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- SPOCK Tool for Constructing Empirical Volcano Diagrams from Catalytic Data.ACS catalysis · 2025Article
- Exploring Supramolecular Frustrated Lewis Pairs.ChemPlusChem · 2025Review
- Microkinetic Molecular Volcano Plots for Enhanced Catalyst Selectivity and Activity Predictions.ACS catalysis · 2024Article
- Engineering Frustrated Lewis Pair Active Sites in Porous Organic Scaffolds for Catalytic COJournal of the American Chemical Society · 2024Article
- Mapping Active Site Geometry to Activity in Immobilized Frustrated Lewis Pair Catalysts.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
4 authors.
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Abstract
The immobilization of molecular catalysts imposes spatial constraints on their active site. We reveal that in bifunctional catalysis such constraints can also be utilized as an appealing handle to boost intrinsic activity through judicious control of the active site geometry. To demonstrate this, we develop a pragmatic approach, based on nonlinear scaling relationships, to map the spatial arrangements of the acid-base components of frustrated Lewis pairs (FLPs) to their performance in the catalytic hydrogenation of CO
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