Evidence map›Paper›PMID 35446458›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Photosensitized [2+2]-Cycloadditions of Alkenylboronates and Alkenes.

Yanyao Liu, Dongshun Ni, Bernard G Stevenson, Vikrant Tripathy, Sarah E Braley, Krishnan Raghavachari, John R Swierk, M Kevin Brown

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.

0numbers the graph read from it
0cells of the map it votes in
27citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

27 citing papers in PubMed.

  1. Article
  2. Reenvisioning the De Mayo Reaction: A Boron-Enabled Cycloaddition Approach.Angewandte Chemie (International ed. in English) · 2026
    Article
  3. Article
  4. Review
  5. Fused 3D boron heterocyclesChemical science · 2026
    Article
  6. Boron-Enabled Stereoselective Synthesis of Polysubstituted Housanes.Journal of the American Chemical Society · 2025
    Article
  7. Article
  8. Article
  9. Article
  10. Facile Synthesis of Housanes by an Unexpected Strategy.Journal of the American Chemical Society · 2025
    Article
  11. Article
  12. Article
  13. Article
  14. Review
  15. Article
  16. Article
  17. Borylated cyclobutanesChemical science · 2024
    Article
  18. Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Yanyao LiuDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA.
Dongshun NiDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA.
Bernard G StevensonDepartment of Chemistry, Binghamton University, 4400 Vestal Parkway East, Binghamton, NY 13902, USA.
Vikrant TripathyDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA.
Sarah E BraleyDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA.
Krishnan RaghavachariDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA.
John R SwierkDepartment of Chemistry, Binghamton University, 4400 Vestal Parkway East, Binghamton, NY 13902, USA.
M Kevin BrownDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA.ORCID http://orcid.org/0000-0002-4993-0917

Funding

Methods and Strategies for Chemical SynthesisR35GM131755 · NIGMS · TRUSTEES OF INDIANA UNIVERSITY · PI Michael Kevin Brown · 2019 to 2026
$4.0M
Directorate for Mathematical and Physical Sciences CHE-1920026Division of Chemistry CHE1554760Division of Chemistry CHE-1726633Division of Chemistry CHE-2047492Division of Chemistry CHE-2102583NIGMS NIH HHS R35 GM131755NIGMS NIH HHS R35GM131755
6 · The paper itself

Abstract

A new strategy for the synthesis of highly versatile cyclobutylboronates via the photosensitized [2+2]-cycloaddition of alkenylboronates and alkenes is presented. The process is mechanistically different from other processes in that energy transfer occurs with the alkenylboronate as opposed to the other alkene. This strategy allows for the synthesis of an array of diverse cyclobutylboronates. The conversion of these adducts to other compounds as well as their utility in the synthesis of melicodenine C is demonstrated.

Identifiers

PMID35446458
PMCPMC9189050

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.