ArticleChemical science2022
Diaryliodonium salts facilitate metal-free mechanoredox free radical polymerizations.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Zeolitic Imidazolate Framework-8 in Piezo-Assisted Mechanochemical Oxidation Reactions.ChemistryOpen · 2026Article
- Mechanochemical atom transfer radical polymerization unlocks functional methacrylate lifecycles of controlled synthesis, force-activated degradation, and depolymerization.Nature communications · 2026Article
- Pushing the limits of mechanoredox RAFT polymerization methods.Polymer chemistry · 2026Article
- Mechanochemical upcycling of poly (vinyl chloride) for alcohol halogenation.Nature communications · 2026Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Two dimensional MoSNature communications · 2025Article
- Aerobic mechanochemical reversible-deactivation radical polymerization.Nature communications · 2024Article
- Liquid-assisted grinding enables a direct mechanochemical functionalization of polystyrene waste.Chemical science · 2024Article
- Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications.Chemical reviews · 2023Review
- Mechanoluminescent Materials Enable Mechanochemically Controlled Atom Transfer Radical Polymerization and Polymer Mechanotransduction.Research (Washington, D.C.) · 2023Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Mechanically-induced redox processes offer a promising alternative to more conventional thermal and photochemical synthetic methods. For macromolecule synthesis, current methods utilize sensitive transition metal additives and suffer from background reactivity. Alternative methodology will offer exquisite control over these stimuli-induced mechanoredox reactions to couple force with redox-driven chemical transformations. Herein, we present the iodonium-initiated free-radical polymerization of (meth)acrylate monomers under ultrasonic irradiation and ball-milling conditions. We explore the kinetic and structural consequences of these complementary mechanical inputs to access high molecular weight polymers. This methodology will undoubtedly find broad utility across stimuli-controlled polymerization reactions and adaptive material design.
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Registered trials
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