Evidence map›Paper›PMID 35440662›Full record

ArticleNature communications2022

The stability of covalent dative bond significantly increases with increasing solvent polarity.

Rabindranath Lo, Debashree Manna, Maximilián Lamanec, Martin Dračínský, Petr Bouř, Tao Wu, Guillaume Bastien, Jiří Kaleta, Vijay Madhav Miriyala, Vladimír Špirko and 3 more

Abstract read
In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed.

  1. Kinetically Stable Boron-Heteroatom Bonds.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Article
  3. Discovery of vasodilatory effects of NaActa pharmacologica Sinica · 2026
    Article
  4. Article
  5. Blue-Shifting Hydridic Hydrogen Bonds in Complexes of (MeThe journal of physical chemistry. A · 2025
    Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Review
  11. Article
  12. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Rabindranath LoInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.ORCID 0000-0002-4436-3618
Debashree MannaInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Maximilián LamanecInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Martin DračínskýInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.ORCID 0000-0002-4495-0070
Petr BouřInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Tao WuInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Guillaume BastienInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Jiří KaletaInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.ORCID 0000-0002-5561-7580
Vijay Madhav MiriyalaInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Vladimír ŠpirkoInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Anna MašínováInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic.
Dana NachtigallováInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic. dana.nachtigallova@uochb.cas.cz.
Pavel HobzaInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo námĕstí 542/2, 16000, Prague, Czech Republic. pavel.hobza@uochb.cas.cz.ORCID 0000-0001-5292-6719

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

It is generally expected that a solvent has only marginal effect on the stability of a covalent bond. In this work, we present a combined computational and experimental study showing a surprising stabilization of the covalent/dative bond in Me

Indexed as

SolventsIonsThermodynamicsIonsSolvents

Identifiers

PMID35440662
PMCPMC9018688

What OpenQuestion holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.