ArticleAngewandte Chemie (International ed. in English)2022
Bonding in a Crystalline Tri-Thorium Cluster: Not σ-Aromatic But Still Unique.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
9 citing papers in PubMed, 26 citations in OpenAlex.
- Field-induced non-linear magnetic responses of all-metal Jellium σ-aromats.Nature communications · 2026Article
- Unusual bonding situations in Th(iv) and U(iv)-Al(iii) pnictogen complexes.Chemical science · 2026Article
- Core-electron contributions to the magnetic response of molecules with heavy elements and their significance in aromaticity assessments.Chemical science · 2024Article
- On the aromaticity of actinide compounds.Nature reviews. Chemistry · 2024Review
- The curious case of the crystalline tri-thorium cluster: cyclic delocalization without aromatic stabilization?RSC advances · 2023Article
- Actinide-lanthanide single electron metal-metal bond formed in mixed-valence di-metallofullerenes.Nature communications · 2023Article
- Magnetic Antiaromaticity─Paratropicity─Does Not Necessarily Imply Instability.The Journal of organic chemistry · 2023Article
- On the Bonding Nature in the Crystalline Tri-Thorium Cluster: Core-Shell Syngenetic σ-Aromaticity.Angewandte Chemie (International ed. in English) · 2022Article
- Bonding in a Crystalline Tri-Thorium Cluster: Not σ-Aromatic But Still Unique.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
1 author at 1 institution in 1 country.
Funding
Abstract
Very recently, Boronski et al. reported the first thorium-thorium bond in a crystalline cluster prepared under normal experimental conditions. By using a range of experimental techniques and computational models, the authors found that the isolated actinide cluster contains at its heart two paired electrons delocalized over the tri-thorium ring. The recorded Raman spectrum allegedly confirmed the existence of a σ-aromatic three-center two-electron bond. In the following we demonstrate that the experimentally observed broad inelastic scattering bands between 60 and 135 cm
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.