ArticleRSC advances2022
Organically tuned white-light emission from two zero-dimensional Cd-based hybrids.
Article in RSC advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 18 citations in OpenAlex.
- Structural, spectroscopic, thermal and biological insights into a new cadmium halide-based organic-inorganic hybrid material.RSC advances · 2026Article
- Urea-functionalized HKUST-1 metal-organic framework for high-performance lead adsorption.RSC advances · 2025Article
- Comprehensive Exploration of Optics and Magnetism in a Hydrothermally Synthesized Nickel(II) Complex.ACS omega · 2024Article
- Tunability of Photovoltaic Functions via Halogen Substitution [(Ade)Molecules (Basel, Switzerland) · 2024Article
- Crystal Chemistry, Optic and Magnetic Characterizations of a New Copper Based Material Templated by Hexahydrodiazepine.ACS omega · 2023Article
- A promising 1D Cd-based hybrid perovskite-type for white-light emission with high-color-rendering index.RSC advances · 2022Article
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Authors and funding
6 authors at 3 institutions in 3 countries.
Funding
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Abstract
In this work, we report two zero-dimensional Cd-based hybrid compounds, denoted CdACP and CdODA, where the Cd atoms adopt tetrahedral geometry. The optical analysis reveals that these materials are classified as wide-gap semi-conductors which makes them suitable for optoelectronic applications. The photoluminescence analysis proves the wavelength dependent white-light emission behavior of the investigated materials. The structural-optical property studies show that, thanks to the heavy halide effect, the CdACP exhibits both fluorescence and room temperature phosphorescence through harvesting triplet states. Meanwhile, in contrast to CdACP, the white light emission from CdODA is purely fluorescence in nature. In fact, within CdODA, both C-H⋯π and N-H⋯N interactions facilitate the intramolecular proton transfer (ESIPT) between the different cations which leads to ultra-fast fluorescence through excited state ESIPT. Under sub-gap excitations, the inorganic sub-lattice is responsible for the blue-green emission through the STE mechanism, while the organic cations contribute by an intense red emission.
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