ArticleRSC advances2021
Transition-metal-free decarboxylative thiolation of stable aliphatic carboxylates.
Article in RSC advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Decarboxylative selenylation of carboxylic acids: a reliable strategy for the synthesis of selenoethers.RSC advances · 2026Review
- Carboxylic Acids as Versatile Precursors: Advances in Decarboxylation Strategies for Modern Organic Synthesis.ACS omega · 2026Review
- Humic acid as a natural catalyst for C-S bond construction: decarbonylative and decarboxylative thioether synthesis.RSC advances · 2025Article
- Sodium thiosulfate-catalysed synthesis of thioethers from aldehydes or carboxylic acids.Royal Society open science · 2025Article
- Frontiers in bond construction: innovative approaches to C-C and carbon-heteroatom (C-S, C-N, C-O, C-Se, C-P) transformations-a review.RSC advances · 2025Review
- Transition metal-free decarboxylative olefination of carboxylic acid salts.Chemical science · 2024Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A transition-metal-free decarboxylative thiolation protocol is reported in which primary, secondary, tertiary (hetero)aryl acetates and α-CN substituted acetates undergo the decarboxylative thiolation smoothly, to deliver a variety of functionalized aryl alkyl sulfides in moderate to excellent yields. Aryl diselenides are also amenable substrates for construction of C-Se bonds under the simple and mild reaction conditions. Moreover, the protocol is successfully applied to the late-stage modification of pharmaceutical carboxylates with satisfactory chemoselectivity and functional-group compatibility.
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Registered trials
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