ArticleRSC advances2021
Iron-catalysed hydroboration of non-activated imines and nitriles: kinetic and mechanistic studies.
Article in RSC advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed, 30 citations in OpenAlex.
- Synthesis, Characterization and Reactivity of Alkyl Iron(II) PCP Pincer Complexes.Organometallics · 2026Article
- Nitrile Hydroboration by Cooperative Iron Catalysis: An Experimental and Computational Study.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Bis(diiminate)-Supported Bimetallic Complexes: Tri-Coordinated Zinc for Nitrile and Carbodiimide Hydroboration.ACS omega · 2025Article
- Imine Reduction with MeMolecules (Basel, Switzerland) · 2021Article
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
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Abstract
Iron-catalysed hydroboration of imines and nitriles has been developed under low catalyst loading (1 mol%) in the presence of HBpin. A wide scope of substrate was found to smoothly undergo hydroboration, including electron releasing/withdrawing and halogen substitution patterns and cyclic substrates which all afforded the corresponding amines in good to excellent yields. Dihydroboration of nitriles was achieved conveniently under solvent free and additive free conditions. Promisingly, this catalytic system is also capable of the hydroboration of challenging ketimine substrates. Preliminary kinetic analysis of imine hydroboration reveals a first-order dependence on catalyst concentration. Both HBpin and 4-fluorophenyl-
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