Evidence map›Paper›PMID 35424012›Full record

ArticleRSC advances2021

Bromotrimethylsilane as a selective reagent for the synthesis of bromohydrins.

Donatella Giomi, Antonella Salvini, Jacopo Ceccarelli, Alberto Brandi

Open access · goldAbstract read
In one paragraph

Article in RSC advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.2field-weighted citation impact, top 56% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 2 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Donatella GiomiDipartimento di Chimica 'Ugo Schiff', Università degli Studi di Firenze Via della Lastruccia 3-13 I-50019 Sesto Fiorentino (Fi) Italy donatella.giomi@unifi.it antonella.salvini@unifi.it.ORCID https://orcid.org/0000-0001-7365-1048
Antonella SalviniDipartimento di Chimica 'Ugo Schiff', Università degli Studi di Firenze Via della Lastruccia 3-13 I-50019 Sesto Fiorentino (Fi) Italy donatella.giomi@unifi.it antonella.salvini@unifi.it.ORCID https://orcid.org/0000-0003-0009-2331
Jacopo CeccarelliDipartimento di Chimica 'Ugo Schiff', Università degli Studi di Firenze Via della Lastruccia 3-13 I-50019 Sesto Fiorentino (Fi) Italy donatella.giomi@unifi.it antonella.salvini@unifi.it.ORCID https://orcid.org/0000-0002-0759-787X
Alberto BrandiDipartimento di Chimica 'Ugo Schiff', Università degli Studi di Firenze Via della Lastruccia 3-13 I-50019 Sesto Fiorentino (Fi) Italy donatella.giomi@unifi.it antonella.salvini@unifi.it.ORCID https://orcid.org/0000-0001-8273-6369
University of Florence · IT

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production of fine chemicals. As glycerol is a relevant by-product in biodiesel production, TMSBr has been also tested as a mediator in transesterification in acidic conditions, providing FAME from castor oil in good yields, along with bromohydrins from glycerol. Subsequently the glycerol conversion was optimized and depending on the reaction conditions, glycerol can be selectively converted into α-monobromohydrin (1-MBH) or α,γ-dibromohydrin (1,3-DBH) in very good yields.

Identifiers

PMID35424012
PMCPMC8697681
OpenAlexW3154459445

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.