ArticleRSC advances2021
Terephthalate and trimesate metal-organic frameworks of Mn, Co, and Ni: exploring photostability by spectroscopy.
Article in RSC advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
4 citing papers in PubMed.
- Silver citrate engineered NiCoRSC advances · 2026Article
- Kinetic and isotherm study of Ni-MOF/Magnetite nanoparticles adsorption capacity as green synthesized adsorbent towards rhodochrome (Kammererite).Scientific reports · 2025Article
- Applications of metal-organic framework-based bioelectrodes.Chemical science · 2022Review
- Metal organic framework derived NaCoScientific reports · 2021Article
Corrections and comments
- Erratum issued
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report a rapid synthesis for the fabrication of terephthalate and trimesate metal-organic frameworks (MOFs) of Mn, Co, and Ni by ultrasonication of organic linkers with freshly prepared metal hydroxides. The MOFs were characterized by various microscopic and spectroscopic techniques to understand their structural, functional, and optical properties. MOFs with low bandgap energy (1.88-2.73 eV) showed strong absorbance in the UV-visible range. MOFs were exposed to UV irradiation for 40 h to understand their photostability. The MOFs showed decreased surface area and porosity with CoBTC as an exception. PXRD was less convincing for exploring functional changes in the UV-irradiated MOFs. XPS predicted changes in the oxidation states of metal nodes, the degradation of the organic linkers, and decarboxylation process in many of the transition MOFs. The study predicted terephthalate-based MOFs as more photostable than corresponding trimesate-based MOFs. This study is one of the first attempts in exploring photostability of MOFs with Mn, Co, and Ni as nodes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.