Evidence map›Paper›PMID 35422117›Full record

ArticleInorganic chemistry2022

Macrocycle-Induced Modulation of Internuclear Interactions in Homobimetallic Complexes.

Laura M Thierer, Sam H Brooks, Alexander B Weberg, Peng Cui, Shaoguang Zhang, Michael R Gau, Brian C Manor, Patrick J Carroll, Neil C Tomson

Abstract read
In one paragraph

Article in Inorganic chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Laura M ThiererRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.
Sam H BrooksRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.
Alexander B WebergRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.ORCID 0000-0001-8421-9760
Peng CuiRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.ORCID 0000-0003-4011-4144
Shaoguang ZhangRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.
Michael R GauRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.ORCID 0000-0002-4790-6980
Brian C ManorRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.
Patrick J CarrollRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.ORCID 0000-0002-8142-7211
Neil C TomsonRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.ORCID 0000-0001-9131-1039

Funding

Modelling Enzymatic Electrostatic Field Effects with Coordination ChemistryR35GM128794 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI Neil Carleton Tomson · 2018 to 2026
$3.4M
NIGMS NIH HHS R35 GM128794
6 · The paper itself

Abstract

A synthetic route has been developed for a series of 3d homobimetallic complexes of Mn, Fe, Co, Ni, and Cu using three different pyridyldiimine and pyridyldialdimine macrocyclic ligands with ring sizes of 18, 20, and 22 atoms. Crystallographic analyses indicate that while the distances between the metals can be modulated by the size of the macrocycle pocket, the flexibility in the alkyl linkers used to construct the macrocycles enables the ligand to adjust the orientation of the PD(A)I fragments in response to the geometry of the [M

Indexed as

Coordination ComplexesMetalsLigandsMagneticsCoordination ComplexesLigandsMetals

Identifiers

PMID35422117
PMCPMC9252315

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.