ArticleAngewandte Chemie (International ed. in English)2022
Enhancing Metalating Efficiency of the Sodium Amide NaTMP in Arene Borylation Applications.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Ligand- and alkali metal identity-effects in ligand-inducedChemical science · 2026Article
- Deprotonative C(spAngewandte Chemie (International ed. in English) · 2026Article
- Regiodivergent Deuteration of Pyridine-Based Heterocycles.Organic letters · 2025Article
- Synthesis and Structure of Neopentyl Sodium: A Hydrocarbon-Soluble Reagent for Controlled Sodiation of Non-Activated Substrates.Angewandte Chemie (International ed. in English) · 2025Article
- Arene Activation by Calcium Hydride/Zinc Amide Equilibration.Journal of the American Chemical Society · 2025Article
- Iron-catalysed direct coupling of organosodium compounds.Nature synthesis · 2025Article
- The Application of Flow Chemistry for the Synthesis of Alkyl Sodium Compounds and Their Transformations with Weinreb Amides and Carboxylic Acids.Organic letters · 2024Article
- The Versatile and StrategicChemical reviews · 2024Review
- Main group metal-mediated strategies for C-H and C-F bond activation and functionalisation of fluoroarenes.Chemical science · 2023Review
- Alkali-metal bases in catalytic hydrogen isotope exchange processes.Catalysis science & technology · 2023Review
- Sodium mediated deprotonative borylation of arenes using sterically demanding B(CHChemical science · 2023Article
- Main Group Catalyzed Arene Borylation: Challenges and Opportunities.ACS catalysis · 2023Article
- Sodium Isopropyl(trimethylsilyl)amide: A Stable and Highly Soluble Lithium Diisopropylamide Mimic.The Journal of organic chemistry · 2022Article
- Enhancing Metalating Efficiency of the Sodium Amide NaTMP in Arene Borylation Applications.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Though LiTMP (TMP=2,2',6,6'-tetramethylpiperidide) is a commonly used amide, surprisingly the heavier NaTMP has hardly been utilised. Here, by mixing NaTMP with tridentate donor PMDETA (N,N,N',N'',N''-pentamethyldiethylenetriamine), we provide structural, and mechanistic insights into the sodiation of non-activated arenes (e.g. anisole and benzene). While these reactions are low yielding, adding B(OiPr)
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Registered trials
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