ReviewAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2022
The Rise of 1,4-BN-Heteroarenes: Synthesis, Properties, and Applications.
Review in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed, 112 citations in OpenAlex.
- Boron-Nitrogen Covalent Bond-Embedded Multiple Resonance Emitters: Synthesis Strategy, Molecular Design, and Optoelectronic Properties.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Article
- Facile Synthesis of Nonalternant π-Conjugated Azaborines via Boron-Deleting Annulation.Journal of the American Chemical Society · 2026Article
- B-N-B Embedded multiple-resonance polyaromatic enabling efficient narrowband electroluminescence.Nature communications · 2026Article
- Organocatalysed three-component modular synthesis of BN isosteres and BN-2,1-azaboranaphthalenes via Wolff-type rearrangement.Nature chemistry · 2026Article
- Comprehensive Review on the Structural Diversity and Versatility of Multi-Resonance Fluorescence Emitters: Advance, Challenges, and Prospects toward OLEDs.Chemical reviews · 2025Review
- COMPAS-4: A Data Set of (BN)Journal of chemical information and modeling · 2025Article
- Frozen-Pair-Type pCCD-Based Methods and Their Double Ionization Variants to Predict Properties of Prototypical BN-Doped Light Emitters.Journal of chemical theory and computation · 2025Article
- Synthesis of quadruply boron-doped acenes with stimuli-responsive multicolor emission.Nature communications · 2024Article
- Highly efficient multi-resonance thermally activated delayed fluorescence material toward a BT.2020 deep-blue emitter.Nature communications · 2024Article
- Stereo effects for efficient synthesis of orange-red multiple resonance emitters centered on a pyridine ring.Chemical science · 2024Article
- Synthesis, Structures, and Chiroptical Properties of NBN-Doped Helicenes with Boron Atoms in the Inner Rims.Precision chemistry · 2024Article
- Borylation-Reduction-Borylation for the Formation of 1,4-Azaborines.Organic letters · 2023Article
- Precise modulation of multiple resonance emitters toward efficient electroluminescence with pure-red gamut for high-definition displays.Science advances · 2023Article
- Amides as modifiable directing groups in electrophilic borylation.Chemical science · 2023Article
- Double boron-embedded multiresonant thermally activated delayed fluorescent materials for organic light-emitting diodes.Communications chemistry · 2022Review
- The Rise of 1,4-BN-Heteroarenes: Synthesis, Properties, and Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
BN-heteroarenes, which employ both boron and nitrogen in aromatic hydrocarbons, have gained great attention in the fields of organic chemistry and materials science. Nevertheless, the extensive studies on BN-heteroarenes are largely limited to 1,2-azaborine-based compounds with B-N covalent bonds, whereas 1,3- and 1,4-BN-heteroarenes are relatively rare due to their greater challenge in the synthesis. Recently, significant progresses have been achieved in the synthesis and applications of BN-heteroarenes featuring 1,4-azaborines, especially driven by their significant potential as multiresonant thermally activated delayed fluorescence (MR-TADF) materials. Therefore, it is timely to review these advances from the chemistry perspective. This review summarizes the synthetic methods and recent achievements of 1,4-azaborine-based BN-heteroarenes and discusses their unique properties and potential applications of this emerging class of materials, highlighting the value of 1,4-BN-heteroarenes beyond MR-TADF materials. It is hoped that this review would stimulate the conversation and cooperation between chemists who are interested in azaborine chemistry and materials scientists working in the fields of organic optoelectronics, metal catalysis, and carbon-based nanoscience etc.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.