ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2022
Grafting Ink for Direct Writing: Solvation Activated Covalent Functionalization of Graphene.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
7 citing papers in PubMed, 24 citations in OpenAlex.
- High-Temperature Single-Photon Emission From Covalently Functionalized van der Waals Heterostructures.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Antibiotics and Antibiotic Resistance Genes in the Environment: Dissemination, Ecological Risks, and Remediation Approaches.Microorganisms · 2025Review
- Electrochemical Functionalization of Graphene-on-Cu(111): Reactivity, Onset Potentials, and Mechanistic Insights.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Orthogonal Functionalization of Oxo-Graphene Nanoribbons.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Chemical Patterning on Nanocarbons: Functionality Typewriting.Molecules (Basel, Switzerland) · 2023Review
- On the role of functional groups in the formation of diazonium based covalent attachments: dendriticRSC advances · 2023Article
- Grafting Ink for Direct Writing: Solvation Activated Covalent Functionalization of Graphene.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
Abstract
Covalent functionalization of graphene (CFG) has shown attractive advantages in tuning the electronic, mechanical, optical, and thermal properties of graphene. However, facile, large-scale, controllable, and highly efficient CFG remains challenging and often involves highly reactive and volatile compounds, requiring complex control of the reaction conditions. Here, a diazonium-based grafting ink consisting of only two components, i.e., an aryl diazonium salt and the solvent dimethyl sulfoxide (DMSO) is presented. The efficient functionalization is attributed to the combination of the solvation of the diazonium cations by DMSO and n-doping of graphene by DMSO, thereby promoting electron transfer (ET) from graphene to the diazonium cations, resulting in the generation of aryl radicals which subsequently react with the graphene. The grafting density of CFG is controlled by the reaction time and very high levels of functionalization, up to the failing of the Tuinstra-Koenig (T-K) relation, while the functionalization layer remains at monolayer height. The grafting ink, effective for days at room temperature, can be used at ambient conditions and renders the patterning CFG by direct writing as easy as writing on paper. In combination with thermal sample treatment, reversible functionalization is possible by subsequent writing/erasing cycles.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.