Evidence map›Paper›PMID 35416383›Full record

ArticleAngewandte Chemie (International ed. in English)2022

The Tris(pentafluorophenyl)methylium Cation: Isolation and Reactivity.

Kurt F Hoffmann, David Battke, Paul Golz, Susanne M Rupf, Moritz Malischewski, Sebastian Riedel

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
2.6field-weighted citation impact, top 10% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed, 31 citations in OpenAlex.

  1. Article
  2. Luminescent Perhalofluoro Trityl Radicals.Journal of the American Chemical Society · 2025
    Article
  3. Review
  4. The Pentafluorophenyl Cation: A Superelectrophile and Diradical.Angewandte Chemie (International ed. in English) · 2025
    Article
  5. Article
  6. Abstraction of Hydride from Alkanes and Dihydrogen by the Perfluorotrityl Cation.Angewandte Chemie (International ed. in English) · 2025
    Article
  7. Introducing AFS ([Al(SOChemical science · 2024
    Article
  8. Article
  9. [Xe(OTeFChemical communications (Cambridge, England) · 2024
    Article
  10. Review
  11. Insights on the Lewis Superacid Al(OTeFChemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  12. The Tris(pentafluorophenyl)methylium Cation: Isolation and Reactivity.Angewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Kurt F HoffmannFachbereich für Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstraße 34/36, 14195, Berlin, Germany.ORCID http://orcid.org/0000-0002-5419-1741
David BattkeFachbereich für Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstraße 34/36, 14195, Berlin, Germany.
Paul GolzFachbereich für Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstraße 34/36, 14195, Berlin, Germany.
Susanne M RupfFachbereich für Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstraße 34/36, 14195, Berlin, Germany.ORCID http://orcid.org/0000-0002-1577-1743
Moritz MalischewskiFachbereich für Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstraße 34/36, 14195, Berlin, Germany.ORCID http://orcid.org/0000-0002-6756-2951
Sebastian RiedelFachbereich für Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstraße 34/36, 14195, Berlin, Germany.ORCID http://orcid.org/0000-0003-4552-5719

Funding

Deutsche Forschungsgemeinschaft SFB 1349 - 387284271H2020 European Research Council HighPotOx
6 · The paper itself

Abstract

Herein, we present two different routes for the synthesis of the perfluorinated trityl cation, which allowed the handling of the free, uncoordinated species in organic solvents for the first time. The usage of the weakly coordinating anion [Al(OTeF

Indexed as

High Hydride AffinityPerfluorinated Trityl CationStrong OxidizerSuperacidsWeakly Coordinating Anions

Identifiers

PMID35416383
PMCPMC9401592
OpenAlexW4223561058

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.