ArticleNature communications2022
A general strategy for heterogenizing olefin polymerization catalysts and the synthesis of polyolefins and composites.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Quantitative Analysis of the Steric Effect in Phosphinophenolate Nickel Catalysts for Ethylene Polymerization.Polymer science & technology (Washington, D.C.) · 2026Article
- A review of immobilized molecular transition metal catalysts for ethylene oligomerization and polymerization reactions.RSC advances · 2026Review
- Unraveling the Reactivity of SiOPolymers · 2025Article
- Advances in High-Temperature Non-Metallocene Catalysts for Polyolefin Elastomers.Materials (Basel, Switzerland) · 2025Review
- Polyethylene-poly(methyl acrylate) Block Copolymers from PACE-SARA ATRP: Utilizing Polyolefin Active Ester Exchange-Based Macroinitiators in Atom Transfer Radical Polymerization.Macromolecules · 2025Article
- Exploring ethylene insertion reaction mechanism in nickel complexes: a comparative study by the reaction force and reaction electronic flux in molecular and SiOJournal of molecular modeling · 2024Article
- Catalyst Editing via Post-Synthetic Functionalization by Phosphonium Generation and Anion Exchange for Nickel-Catalyzed Ethylene/Acrylate Copolymerization.Journal of the American Chemical Society · 2024Article
- Recent Advancements in the Synthesis of Ultra-High Molecular Weight Polyethylene via Late Transition Metal Catalysts.Polymers · 2024Review
- Recent Advances in Nickel Catalysts with Industrial Exploitability for Copolymerization of Ethylene with Polar Monomers.Polymers · 2024Review
- Ethylene/Polar Monomer Copolymerization by [N, P] Ti Complexes: Polar Copolymers with Ultrahigh-Molecular Weight.ACS omega · 2024Article
- Light, Heat, and Force-Responsive Polyolefins.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Trends in Structure and Ethylene Polymerization Reactivity of Transition-Metal Permethylindenyl-phenoxy (PHENI*) Complexes.Organometallics · 2024Article
- Synthesis of Ultra-High-Molecular-Weight Polyethylene by Transition-Metal-Catalyzed Precipitation Polymerization.Precision chemistry · 2024Article
- Synthesis of α-Diimine Complex Enabling Rapidly Covalent Attachment to Silica Supports and Application of Homo-/Heterogeneous Catalysts in Ethylene Polymerization.International journal of molecular sciences · 2023Article
- Photodegradable polar-functionalized polyethylenes.National science review · 2023Article
- A co-anchoring strategy for the synthesis of polar bimodal polyethylene.Nature communications · 2023Article
- Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts.Polymers · 2022Review
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The heterogenization of homogeneous metal complexes on solid supports presents an efficient strategy for bridging homogeneous catalysts with industrially-preferred heterogeneous catalysts; however, a series of drawbacks restrict their implementation in olefin polymerization, particularly for copolymerization with polar comonomers. In this contribution, we report an ionic anchoring strategy that is highly versatile, generally applicable to different systems, and enables strong catalyst-support interactions while tolerating various polar functional groups. In addition to greatly enhanced polymerization properties, the supported catalysts achieved higher comonomer incorporation than their unsupported counterparts. This strategy enabled efficient polymerization at high temperatures at large scale and great control over product morphology, and the facile synthesis of polyolefin composites. More importantly, the dispersion of different fillers in the polyolefin matrix produced great material properties even at low composite loadings. It is expected that this strategy will find applications in different catalytic systems and the synthesis of advanced engineering materials.
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