ArticleAngewandte Chemie (International ed. in English)2022
A Well-Defined Anionic Dicopper(I) Monohydride Complex that Reacts like a Cluster.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Protonation-Induced Electron Density Redistribution Facilitates Aggregation in PNNP Dicopper Hydride Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Long-range metal-metal cooperative nitrile activation in 1,8-diazaanthracene-supported dicopper complexes.Chemical communications (Cambridge, England) · 2026Article
- Combined Metal-Metal and Metal-Ligand Cooperativity in Dicopper-Catalyzed Azide-Alkyne Cycloaddition Reactions.Organometallics · 2025Article
- Chloride, Alkoxide, or Silicon: The Bridging Ligand Dictates the Spin State in Dicobalt Expanded Pincer Complexes.Organometallics · 2025Article
- Mechanistic Investigation into Copper(I) Hydride Catalyzed Formic Acid Dehydrogenation.ACS catalysis · 2024Article
- Controlling the Size of Molecular Copper Clusters Supported by a Multinucleating Macrocycle.Inorganic chemistry · 2024Article
- Quantification of the Steric Properties of 1,8-Naphthyridine-Based Ligands in Dinuclear Complexes.Organometallics · 2023Article
- E-selective Semi-hydrogenation of Alkynes under Mild Conditions by a Diruthenium Hydride Complex.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- A Well-Defined Anionic Dicopper(I) Monohydride Complex that Reacts like a Cluster.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
5 authors.
Funding
Abstract
Low-nuclearity copper hydrides are rare and few well-defined dicopper hydrides have been reported. Herein, we describe the first example of a structurally characterized anionic dicopper hydride complex. This complex does not display typical reactivity associated with low-nuclearity copper hydrides, such as alcoholysis or insertion reactions. Instead, its stoichiometric and catalytic reactivity is akin to that of copper hydride clusters. The distinct reactivity is ascribed to the robust dinuclear core that is bound tightly within the dinucleating ligand scaffold.
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