ArticleNanomaterials (Basel, Switzerland)2022
Bromide and Chloride Ionic Liquids Applied to Enhance the Vulcanization and Performance of Natural Rubber Biocomposites Filled with Nanosized Silica.
Article in Nanomaterials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed, 19 citations in OpenAlex.
- Article
- Elastomeric Biocomposites of Natural Rubber Containing Biosynthesized Zinc Oxide.International journal of molecular sciences · 2025Article
- Multifunctional Applications of Ionic Liquids in Polymer Materials: A Brief Review.Molecules (Basel, Switzerland) · 2023Review
- Potential Utilization of Ground Eggshells as a Biofiller for Natural Rubber Biocomposites.Materials (Basel, Switzerland) · 2023Article
- The Potential Application of Starch and Walnut Shells as Biofillers for Natural Rubber (NR) Composites.International journal of molecular sciences · 2022Article
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Authors and funding
2 authors at 1 institution in 1 country.
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Abstract
In this study, the possibility of using ionic liquids (ILs) as auxiliary substances improving the vulcanization and physicochemical properties of natural rubber (NR) biocomposites filled with nanosized silica was investigated. Hence, the influence of ILs with bromide and chloride anions and various cations, i.e., alkylimidazolium, alkylpyrrolidinium and alkylpiperidinium cation, on the curing characteristics and crosslink density of NR compounds was determined. Furthermore, the effect of nanosized silica and ILs on the functional properties of the obtained vulcanizates, including mechanical properties under static and dynamic conditions, hardness, thermal stability and resistance to thermo-oxidative aging, were explored. Applying nanosized silica improved the processing safety of NR compounds but significantly increased the optimal vulcanization time compared to the unfilled rubber. ILs significantly improved the cure characteristics of NR compounds by increasing the rate of vulcanization and the crosslink density of NR biocomposites. Consequently, the tensile strength and hardness of the vulcanizates significantly increased compared to that without ILs. Moreover, the use of nanosized silica and ILs had a favorable impact on the thermal stability of the vulcanizates and their resistance to prolonged thermo-oxidation.
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