ArticleChemical communications (Cambridge, England)2022
Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand.
Article in Chemical communications (Cambridge, England), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Superbasic Anionic Calcium Alkyl Complexes: Templated Twofold Deprotonation of Benzene.Angewandte Chemie (International ed. in English) · 2025Article
- Arene Activation by Calcium Hydride/Zinc Amide Equilibration.Journal of the American Chemical Society · 2025Article
- On the deprotonation of chlorothiazide.Acta crystallographica. Section C, Structural chemistry · 2025Article
- Main group metal-mediated strategies for C-H and C-F bond activation and functionalisation of fluoroarenes.Chemical science · 2023Review
- Applying Na/Co(II) bimetallic partnerships to promote multiple Co-H exchanges in polyfluoroarenes.Chemical communications (Cambridge, England) · 2023Article
- Synthesis and Catalysis of Anionic Amido Iron(II) Complexes.ChemCatChem · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Combining a bulky bis(amide) and a reactive one-coordinate TMP (2,2,6,6-tetramethylpiperidide) ligand, a new mixed K/Zn heteroleptic base has been developed for regioselective zincation of fluoroarenes. This special ligand set allows for trapping and structural authentication of the first intermediates of direct Zn-H exchange of fluoroarenes obtained
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Registered trials
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