ArticleThe journal of physical chemistry letters2022
Cavity-Modified Unimolecular Dissociation Reactions via Intramolecular Vibrational Energy Redistribution.
Article in The journal of physical chemistry letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
18 citing papers in PubMed.
- A macroscopic condensation theory for vibrational strong coupling effects.Nature communications · 2026Article
- Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- Theoretical and quantum mechanical deconstruction of vibrational energy transfer pathways modified by collective vibrational strong coupling.Nature communications · 2025Article
- Polariton mediated electron transfer under the collective molecule-cavity coupling regime.Chemical science · 2025Article
- Theoretical Insights into the Resonant Suppression Effect in Vibrational Polariton Chemistry.Journal of the American Chemical Society · 2025Article
- Leaky Coupled Waveguide-Plasmon Modes for Enhanced Light-Matter Interaction.Sensors (Basel, Switzerland) · 2025Article
- Revealing the Ultrafast Energy Transfer Pathways in Energetic Materials: Time-Dependent and Quantum State-Resolved.JACS Au · 2024Article
- Exploring the impact of vibrational cavity coupling strength on ultrafast CN +Nanophotonics (Berlin, Germany) · 2024Article
- Probing the anharmonicity of vibrational polaritons with double-quantum two-dimensional infrared spectroscopy.Nanophotonics (Berlin, Germany) · 2024Article
- Resonance theory of vibrational polariton chemistry at the normal incidence.Nanophotonics (Berlin, Germany) · 2024Article
- Theoretical formulation of chemical equilibrium under vibrational strong coupling.Nature communications · 2024Article
- Understanding Polaritonic Chemistry from Ab Initio Quantum Electrodynamics.Chemical reviews · 2023Review
- How Quantum is the Resonance Behavior in Vibrational Polariton Chemistry?The journal of physical chemistry letters · 2023Article
- Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics.Chemical reviews · 2023Review
- Manipulating hydrogen bond dissociation rates and mechanisms in water dimer through vibrational strong coupling.Nature communications · 2023Article
- Quantum dynamical effects of vibrational strong coupling in chemical reactivity.Nature communications · 2023Article
- Multimode polariton effects on molecular energy transport and spectral fluctuations.Communications chemistry · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
While the emerging field of vibrational polariton chemistry has the potential to overcome traditional limitations of synthetic chemistry, the underlying mechanism is not yet well understood. Here, we explore how the dynamics of unimolecular dissociation reactions that are rate-limited by intramolecular vibrational energy redistribution (IVR) can be modified inside an infrared optical cavity. We study a classical model of a bent triatomic molecule, where the two outer atoms are bound by anharmonic Morse potentials to the center atom coupled to a harmonic bending mode. We show that an optical cavity resonantly coupled to particular anharmonic vibrational modes can interfere with IVR and alter unimolecular dissociation reaction rates when the cavity mode acts as a reservoir for vibrational energy. These results lay the foundation for further theoretical work toward understanding the intriguing experimental results of vibrational polaritonic chemistry within the context of IVR.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.