ArticleChemical science2022
Electrochemical oxidative N-H/P-H cross-coupling with H
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Easy Access to Fused Tricyclic Quinoline Derivatives through Metal-Free Electrocatalytic [4 + 2] Annulation.ACS organic & inorganic Au · 2024Article
- Electrochemical-induced phosphorylation of arenols and tyrosine containing oligopeptides.iScience · 2024Article
- Efficient and Sustainable Electrosynthesis ofJACS Au · 2024Article
- The Backbone of Success of P,N-Hybrid Ligands: Some Recent Developments.Molecules (Basel, Switzerland) · 2022Review
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Authors and funding
7 authors.
Funding
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Abstract
Tertiary phosphines(iii) find widespread use in many aspects of synthetic organic chemistry. Herein, we developed a facile and novel electrochemical oxidative N-H/P-H cross-coupling method, leading to a series of expected tertiary phosphines(iii) under mild conditions with excellent yields. It is worth noting that this electrochemical protocol features very good reaction selectivity, where only a 1 : 1 ratio of amine and phosphine was required in the reaction. Moreover, this electrochemical protocol proved to be practical and scalable. Mechanistic insights suggested that the P radical was involved in this reaction.
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Registered trials
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