ArticleJACS Au2022
Electrocatalytic Semihydrogenation of Alkynes with [Ni(bpy)
Article in JACS Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Electroreduction of Activated Esters Catalyzed by a Manganese Complex.Organometallics · 2026Article
- Nickel/Photoredox-catalyzed diastereoselective semihydrogenation of alkynes using a carboxylic acid as a cooperative ligand and hydrogen surrogate.Nature communications · 2026Article
- Mediator-Enabled Co-CatalyzedACS catalysis · 2026Article
- Electrochemical reduction of unsaturated carbon-carbon bonds via 3d transition-metal catalysis.Beilstein journal of organic chemistry · 2026Review
- Earth-abundant Ni-Zn nanocrystals for efficient alkyne semihydrogenation catalysis.Nature communications · 2025Article
- Electrochemical cobalt-catalyzed semi-deuteration of alkynes to access deuterated Z-alkenes.Nature communications · 2025Article
- Spontaneous ligand loss by soft landed [Ni(bpy)Chemical science · 2024Article
- Electrocatalytic Semihydrogenation of Terminal Alkynes Using Ligand-Based Transfer of Protons and Electrons.Journal of the American Chemical Society · 2024Article
- Hydride-Free Hydrogenation: Unraveling the Mechanism of Electrocatalytic Alkyne Semihydrogenation by Nickel-Bipyridine Complexes.Journal of the American Chemical Society · 2023Article
- Electro-Synthesis of Organic Compounds with Heterogeneous Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Stereoselective Semi-Hydrogenations of Alkynes by First-Row (3d) Transition Metal Catalysts.ChemCatChem · 2022Review
- Electrocatalysis with Molecular Transition-Metal Complexes for Reductive Organic Synthesis.JACS Au · 2022Review
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electrifying the production of base and fine chemicals calls for the development of electrocatalytic methodologies for these transformations. We show here that the semihydrogenation of alkynes, an important transformation in organic synthesis, is electrocatalyzed at room temperature by a simple complex of earth-abundant nickel, [Ni(bpy)
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.