ArticleNature communications2022
The promotion effect of π-π interactions in Pd NPs catalysed selective hydrogenation.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Humidity-Guided In Situ Polymerization for Controlled Formation of Smooth, Oriented Covalent Organic Framework Films.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Lignin-degrading-inspired dehydrogenative photocatalysis via reductive quenching of donor-acceptor covalent organic framework.Science advances · 2026Article
- Spike-Embedded Nanocatalysts via Metal-Directed Carbonization for Highly Efficient and Robust Semi-Hydrogenation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Ligand-Intercalated MOFs Enable Reaction-Pathway Engineering in Biomass Electrooxidation via Steric and π-Electronic Microenvironment Control.Angewandte Chemie (International ed. in English) · 2026Article
- Two-Dimensional Metastable-Phase Nickel Hexagonal Nanosheets for Highly-Performance Electrochemical Acetone Hydrogenation.Nature communications · 2025Article
- Straightforward construction of functionalized γ-lactams via conjugated-engineered covalent organic framework photocatalysed cascade reactions.Nature communications · 2025Article
- Revisiting the Most Stable Structures of the Benzene Dimer.International journal of molecular sciences · 2024Article
- Molecular Engineering and Morphology Control of Covalent Organic Frameworks for Enhancing Activity of Metal-Enzyme Cascade Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Iron Active Center Coordination Reconstruction in Iron Carbide Modified on Porous Carbon for Superior Overall Water Splitting.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Composite materials based on covalent organic frameworks for multiple advanced applications.Exploration (Beijing, China) · 2023Review
- Temperature-induced formation of Pd nanoparticles in heterogeneous nanobiohybrids: application in C-H activation catalysis.Nanoscale advances · 2023Article
- Microenvironment engineering of supported metal nanoparticles for chemoselective hydrogenation.Chemical science · 2022Review
- Underlying Mechanisms of Reductive Amination on Pd-Catalysts: The Unique Role of Hydroxyl Group in Generating Sterically Hindered Amine.International journal of molecular sciences · 2022Article
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The utilization of weak interactions to improve the catalytic performance of supported metal catalysts is an important strategy for catalysts design, but still remains a big challenge. In this work, the weak interactions nearby the Pd nanoparticles (NPs) are finely tuned by using a series of imine-linked covalent organic frameworks (COFs) with different conjugation skeletons. The Pd NPs embedded in pyrene-COF are ca. 3 to 10-fold more active than those in COFs without pyrene in the hydrogenation of aromatic ketones/aldehydes, quinolines and nitrobenzene, though Pd have similar size and surface structure. With acetophenone (AP) hydrogenation as a model reaction, systematic studies imply that the π-π interaction of AP and pyrene rings in the vicinity of Pd NPs could significantly reduce the activation barrier in the rate-determining step. This work highlights the important role of non-covalent interactions beyond the active sites in modulating the catalytic performance of supported metal NPs.
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