ArticleChemistry, an Asian journal2022
A Catalogue of Orthogonal Complementary Ligand Pairings for Palladium(II) Complexes.
Article in Chemistry, an Asian journal, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Supramolecular self-assembly by layering orthogonality to program identity, connectivity and conformation.Nature reviews. Chemistry · 2026Review
- Design Rules for Controlling Connectivity, Topology, and Sorting Using Hydrogen-Bonded Pairs and Aromatic Components in Palladium(II)-Based Interlocked and Foldameric Systems.Angewandte Chemie (International ed. in English) · 2026Article
- Coordination-Driven Orthogonal Ligand Pairings through Dual Hydrogen-Bonding/π-π Interaction Complementarity.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Selective Sequestration of Palladium(II) Cations Using a Supramolecular Polymer Approach.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- A Catalogue of Orthogonal Complementary Ligand Pairings for Palladium(II) Complexes.Chemistry, an Asian journal · 2022Article
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Abstract
Molecular recognition is a form of information transfer, seen in the base pairing in DNA which is derived from the identity (acceptor or donor) and number of hydrogen bond sites within each base. Here we report bis-ligand palladium(II) complexes that exhibit similar complementarity. Pd(II) has square planar four-coordinate geometry, giving control over ligand orientation and denticity. Pairings were developed using ligand denticity (3 : 1 or 2 : 2), and hydrogen bond capability (AA:DD or AD:DA) or lack thereof. Five pairings were investigated, with two sets of four being found fully orthogonal. The two 3 : 1 pairings exhibited limited ligand exchange. The extent of this exchange varied dependant on solvent from 2 : 1 (desired to undesired) to 6 : 1. A reliable and varied set of ligand pairs have therefore been developed for bis-ligand coordination sphere engineering in pursuit of sorting for complex molecular architectures and molecular-level information storage and transfer events.
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