ArticleAngewandte Chemie (International ed. in English)2022
Expanding the Scope of Metastable Species in Hydrogen Bonding-Directed Supramolecular Polymerization.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Supramolecular Chiral Assemblies from Benzoselenadiazole-Alanine-Acylhydrazone Conjugates Enable Cardioprotection.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Pathway Complexity in Naphthalene Diimide Supramolecular Polymers: Interruption by an Aromatic Solvent.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- One- and Two-Dimensional Polymorphism in a Hydrogen-Bonding Bis-Ureido-Squaramide.Angewandte Chemie (International ed. in English) · 2026Article
- Switchable supramolecular polymers of a Pt(II) complexRSC advances · 2025Article
- Consecutive Complex Aggregation Pathway in Covalent Helical Polymer-Metal Complexes: Nanospheres with Controlled P/M Macroscopic Chirality.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- A coopetition-driven strategy of parallel/perpendicular aromatic stacking enabling metastable supramolecular polymerization.Nature communications · 2024Article
- Controlling Helical Asymmetry in Supramolecular Copolymers byJournal of the American Chemical Society · 2023Article
- Stereomutation and chiroptical bias in the kinetically controlled supramolecular polymerization of cyano-luminogens.Chemical science · 2022Article
- Luminescence and Length Control in Nonchelated dAngewandte Chemie (International ed. in English) · 2022Article
- Expanding the Scope of Metastable Species in Hydrogen Bonding-Directed Supramolecular Polymerization.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
4 authors.
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Abstract
We reveal unique hydrogen (H-) bonding patterns and exploit them to control the kinetics, pathways and length of supramolecular polymers (SPs). New bisamide-containing monomers were designed to elucidate the role of competing intra- vs. intermolecular H-bonding interactions on the kinetics of supramolecular polymerization (SP). Remarkably, two polymerization-inactive metastable states were discovered. Contrary to previous examples, the commonly assumed intramolecularly H-bonded monomer does not evolve into intermolecularly H-bonded SPs via ring opening, but rather forms a metastable dimer. In this dimer, all H-bonding sites are saturated, either intra- or intermolecularly, hampering elongation. The dimers exhibit an advantageous preorganization, which upon opening of the intramolecular portion of the H-bonding motif facilitates SP in a consecutive process. The retardation of spontaneous self-assembly as a result of two metastable states enables length control in SP by seed-mediated growth.
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