ArticleJournal of the American Chemical Society2022
Elucidating the Mechanism of Excited-State Bond Homolysis in Nickel-Bipyridine Photoredox Catalysts.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 46 papers.
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Who cites it
46 citing papers in PubMed, 133 citations in OpenAlex.
- DiploPhos: A Hemilabile Bisphosphine for Sterically Hindered Ni-Catalyzed Suzuki-Miyaura Couplings.ACS catalysis · 2026Article
- Unlocking Distinct Excited States of a Nickel(II) Complex Without Modulating the Primary Coordination Sphere.JACS Au · 2026Article
- Ultrafast excited-state proton transfer dynamics using linearized pair-density functional theory.Chemical science · 2026Article
- Low-Energy Light-Driven Excited-State Palladium Catalysis: Cross-Coupling of PyridineOrganic letters · 2026Article
- Mechanistic Design in Photocatalysis.Accounts of chemical research · 2026Article
- Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross-Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Direct enantioselective C(spNature chemistry · 2026Article
- Multireference Modeling Reveals the Origins of L‑Edge X‑ray Absorption Features in Photoredox-Active Nickel Complexes.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Expanding Thermodynamic and Kinetic Frontiers in Molecular Photocatalysis.ACS central science · 2026Review
- Predictive, Data-Driven Design of Red-Light Photoredox Catalysts for C─Heteroatom Bond Formation.Angewandte Chemie (International ed. in English) · 2026Article
- Ultrafast Population and Structural Dynamics of a Ni-Bipyridine Photoredox Catalyst Reveal a Significant Deactivation Pathway.The journal of physical chemistry letters · 2026Article
- Advances in NiACS catalysis · 2026Review
- Dual Catalytic Enantioconvergent Carbamoylation of Aziridines.Journal of the American Chemical Society · 2025Article
- Reactivity Studies of Bipyridine-Ligated Nickel(I) and Nickel(0) Complexes Inform the Mechanism in Modern Cross-Coupling Reactions.Journal of the American Chemical Society · 2025Article
- Light-Promoted C(spJournal of the American Chemical Society · 2025Article
- Ligand-to-Metal Charge Transfer of Ag(II) CFAngewandte Chemie (International ed. in English) · 2025Article
- Breaking Kasha's Rule to Enable Higher Reactivity in Photoredox Catalysis.Journal of the American Chemical Society · 2025Article
- Probing the Oxidative Addition Transition State in Nickel Metallaphotoredox Catalysis Using IntramolecularJournal of the American Chemical Society · 2025Article
- Photolytic activation of NiNature communications · 2025Article
- Evidence for a Unifying NiJournal of the American Chemical Society · 2025Article
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Authors and funding
6 authors at 1 institution in 1 country.
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Abstract
Ni 2,2'-bipyridine (bpy) complexes are commonly employed photoredox catalysts of bond-forming reactions in organic chemistry. However, the mechanisms by which they operate are still under investigation. One potential mode of catalysis is via entry into Ni(I)/Ni(III) cycles, which can be made possible by light-induced, excited-state Ni(II)-C bond homolysis. Here, we report experimental and computational analyses of a library of Ni(II)-bpy aryl halide complexes, Ni(
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