ArticleACS applied materials & interfaces2022
Tuning the Activity-Stability Balance of Photocatalytic Organic Materials for Oxidative Coupling Reactions.
Article in ACS applied materials & interfaces, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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9 citing papers in PubMed, 38 citations in OpenAlex.
- Design and Application of a Phenanthroline-Based Covalent Triazine Framework with Cu(I) for the Heterogeneous Synthesis of 2-Aminobenzothiazoles.ACS applied materials & interfaces · 2026Article
- Polystyrene-bound thioxanthone - a heterogeneous photocatalyst for alcohol oxidationCatalysis science & technology · 2026Article
- Structural and Interfacial Characterization of a Photocatalytic Titanium MOF-Phosphate Glass Composite.ACS applied materials & interfaces · 2025Article
- Rapid Formation of Vinylene-Linked Covalent Organic Frameworks Promoted by Dipole Moment.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- Photocatalytic systems: reactions, mechanism, and applications.RSC advances · 2024Review
- Synthesis of aromatic polynitroso compounds: Towards functional azodioxy-linked porous polymers.Heliyon · 2023Article
- Stabilized Chiral Organic Material Containing BINAP Oxide Units as a Heterogeneous Asymmetric Organocatalyst for Allylation of Aldehydes.ACS applied materials & interfaces · 2023Article
- Tunable Photocatalytic Selectivity by Altering the Active Center Microenvironment of an Organic Polymer Photocatalyst.ACS applied materials & interfaces · 2023Article
- State-of-the-Art Advancements in Photocatalytic Hydrogenation: Reaction Mechanism and Recent Progress in Metal-Organic Framework (MOF)-Based Catalysts.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
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4 authors at 1 institution in 1 country.
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Abstract
Three materials containing a photoactive unit, 10-phenyl phenothiazine (PTH), have been studied for the visible light-mediated oxidative coupling of amines. In particular, the materials considered are assembled through the condensation of extended polyimine, polyhydrazone, or polytriazine frameworks. These three materials present different stabilities in the presence of strong nucleophiles such as amines, which is a key factor for efficient catalytic performance. In the series of materials reported herein, the triazine-based material shows the optimal compromise between activity and stability when studied for the oxidative coupling of amines, achieving imine products. Accordingly, while significant leaching of molecular active fragments is ruled out for triazine-based polymers, other materials of the series show a significant chemical erosion as a result of the reaction with the amine substrates. Consequently, only a triazine-based material allows performing several catalytic cycles (up to seven) with yields higher than 80%. The applicability of this heterogeneous catalyst has been proven with a variety of substrates, confirming its stability and obtaining diverse imine coupling products with excellent yields.
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