ArticleJournal of the American Chemical Society2022
Chemoselective (Hetero)Arene Electroreduction Enabled by Rapid Alternating Polarity.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
31 citing papers in PubMed, 121 citations in OpenAlex.
- N-Aryl Acridone Derivatives as Effective Catalysts for Energy Transfer Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Energy-Transfer Catalysis Enables the Birch-Type Reduction of 2-Pyridones.Angewandte Chemie (International ed. in English) · 2026Article
- Floquet States of Chemoselective Alternating Current Electrosynthesis.Journal of the American Chemical Society · 2026Article
- Asymmetric Reduction of Unactivated Alkenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Applying asymmetric-waveform alternating current in nickel-catalyzed asymmetric reductive cross-coupling.Nature communications · 2026Article
- From Waste to Value: Kolbe Electrolysis for the Sustainable Production of Fuels and Chemicals.ChemSusChem · 2026Review
- Dearomative syn-1,4-hydroalkylation and C(spNature chemistry · 2026Article
- Paired Pulsed Decarboxylative Hydroxylation Designed by Online Electrochemistry-Mass Spectrometry.Journal of the American Chemical Society · 2025Article
- Origin of Selectivity in Alternating Current-Enabled Partial Reduction of (Hetero)Arenes: A Case Study of Two Consecutive Irreversible Electrochemical Steps.Journal of the American Chemical Society · 2025Article
- Unlocking a Nano-Aluminum Oxide Lewis Acid Layer as the Electrocatalyst for Hydrogenation of Thiophene and Other Arenes.Journal of the American Chemical Society · 2025Article
- Photocatalytic Hydrogenation of Quinolines to Form 1,2,3,4-Tetrahdyroquinolines Using Water as the Hydrogen Atom Donor.Angewandte Chemie (International ed. in English) · 2025Article
- Building lactams by highly selective hydrodeoxygenation of cyclic imides using an alumina-supported AgRe bimetallic nanocatalyst.Nature communications · 2025Article
- Scaling Organic Electrosynthesis: The Crucial Interplay between Mechanism and Mass Transport.ACS central science · 2025Article
- Atmosphere Effects on Arene Reduction with Lithium and Ethylenediamine in THF.The Journal of organic chemistry · 2025Article
- Bro̷nsted Acid-Catalyzed Reduction of Furans.Journal of the American Chemical Society · 2025Article
- Stereoselective amino alcohol synthesis via chemoselective electrocatalytic radical cross-couplings.Nature chemistry · 2025Article
- Mild Photochemical Reduction of Alkenes and Heterocycles via Thiol-Mediated Formate Activation.Organic letters · 2024Article
- Photochemical dearomative skeletal modifications of heteroaromatics.Chemical Society reviews · 2024Review
- Intricacies of Mass Transport during Electrocatalysis: A Journey through Iron Porphyrin-Catalyzed Oxygen Reduction.Journal of the American Chemical Society · 2024Article
- Total Synthesis of Dragocins A-C through Electrochemical Cyclization.Angewandte Chemie (International ed. in English) · 2024Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
Abstract
Conventional chemical and even electrochemical Birch-type reductions suffer from a lack of chemoselectivity due to a reliance on alkali metals or harshly reducing conditions. This study reveals that a simpler avenue is available for such reductions by simply altering the waveform of current delivery, namely rapid alternating polarity (rAP). The developed method solves these issues, proceeding in a protic solvent, and can be easily scaled up without any metal additives or stringently anhydrous conditions.
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.