ArticleNature nanotechnology2022
Fast and selective reduction of nitroarenes under visible light with an earth-abundant plasmonic photocatalyst.
Article in Nature nanotechnology, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
What it found
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Who cites it
24 citing papers in PubMed.
- Breaking steric hindrance restriction: compressed metal bonds realizing deep-level orbital delocalization.National science review · 2026Article
- Nonmetallic plasmonic Al-doped WNature communications · 2026Article
- Advances in metal nanoparticle-based catalysts for nitroarene reduction: from mechanistic understanding to sustainable design.RSC advances · 2026Review
- Biomimetic synthesis of chitosan-stabilized palladium nanoparticles for biomedical and catalytic applications.RSC advances · 2026Article
- Engineering of Optoelectronic Devices for Renewable Energy Applications.Micromachines · 2026Review
- Energy-Resolved Femtosecond Dynamics of Plasmon-Induced Hole Injection at Au/GaN Heterointerfaces.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Eco-Friendly Synthesis of AuPd Bimetallic Nanoparticles UsingACS omega · 2026Article
- A recyclable dendrimeric Ni nanocatalyst anchored on magnetic nanoparticles for the green reduction of nitroarene pollutants and one-pot synthesis of imines.Scientific reports · 2026Article
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- Article
- Atomic Scale Engineering of Multivalence-State Palladium Photocatalyst for Transfer Hydrogenation with Water as a Proton Source.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Plasmonic catalysis with bi-resonant noble metal-CuFeSNanotechnology · 2025Article
- Modulating Iron Crystals with Lattice Chalcophile-Siderophile Elements for Selective Dechlorinations Over Hydrogen Evolution.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Colloidal quantum dots: surface and interface engineering for light-driven hydrogen production.RSC advances · 2025Review
- Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite.Scientific reports · 2025Article
- Selective hydrogenation of nitro compounds to amines by coupled redox reactions over a heterogeneous biocatalyst.Nature communications · 2024Article
- Efficient reduction-oxidation coupling degradation of nitroaromatic compounds in continuous flow processes.Nature communications · 2024Article
- Electron transfer and energy exchange between a covalent organic framework and CuFeSJournal of materials chemistry. C · 2024Article
- Condensed Matter Systems Exposed to Radiation: Multiscale Theory, Simulations, and Experiment.Chemical reviews · 2024Review
- Versatile synthesis of nano-icosapodsChemical science · 2023Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
Reduction of nitroaromatics to the corresponding amines is a key process in the fine and bulk chemicals industry to produce polymers, pharmaceuticals, agrochemicals and dyes. However, their effective and selective reduction requires high temperatures and pressurized hydrogen and involves noble metal-based catalysts. Here we report on an earth-abundant, plasmonic nano-photocatalyst, with an excellent reaction rate towards the selective hydrogenation of nitroaromatics. With solar light as the only energy input, the chalcopyrite catalyst operates through the combined action of hot holes and photothermal effects. Ultrafast laser transient absorption and light-induced electron paramagnetic resonance spectroscopies have unveiled the energy matching of the hot holes in the valence band of the catalyst with the frontier orbitals of the hydrogen and electron donor, via a transient coordination intermediate. Consequently, the reusable and sustainable copper-iron-sulfide (CuFeS
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Registered trials
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