Evidence map›Paper›PMID 35344253›Full record

ReviewAngewandte Chemie (International ed. in English)2022

Visible-Light-Induced, Single-Metal-Catalyzed, Directed C-H Functionalization: Metal-Substrate-Bound Complexes as Light-Harvesting Agents.

Chao Pei, Claire Empel, Rene M Koenigs

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Review
  5. Recent Advances in Visible Light Induced Palladium Catalysis.Angewandte Chemie (International ed. in English) · 2024
    Review
  6. Article
  7. Article
  8. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Chao PeiRWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, 52074, Aachen, Germany.
Claire EmpelRWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, 52074, Aachen, Germany.ORCID 0000-0002-9362-7755
Rene M KoenigsRWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, 52074, Aachen, Germany.ORCID 0000-0003-0247-4384

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

C-H functionalization represents one of the most rapidly advancing areas in organic synthesis and is regarded as one of the key concepts to minimize the ecological and economic footprint of organic synthesis. The ubiquity and low reactivity of C-H bonds in organic molecules, however, poses several challenges, and often necessitates harsh reaction conditions to achieve this goal, although it is highly desirable to achieve C-H functionalization reactions under mild conditions. Recently, several reports uncovered a conceptually new approach towards C-H functionalization, where a single transition-metal complex can be used as both the photosensitizer and catalyst to promote C-H bond functionalization in the absence of an exogeneous photosensitizer. In this Minireview, we will provide an overview on recent achievements in C-H functionalization reactions, with an emphasis on the photochemical modulation of the reaction mechanism using such catalysts.

Indexed as

Coordination ComplexesTransition ElementsCatalysisMetalsPhotosensitizing AgentsCoordination ComplexesMetalsPhotosensitizing AgentsTransition ElementsC−H FunctionalizationComputational ChemistryPhotocatalysisRhodiumRuthenium

Identifiers

PMID35344253
PMCPMC9401074

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.