ArticleChemical science2022
Electrooxidative palladium- and enantioselective rhodium-catalyzed [3 + 2] spiroannulations.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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14 citing papers in PubMed, 88 citations in OpenAlex.
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- Electrochemical Enantioselective Ruthenium(II)-Catalyzed C-H Activations to Atropostable Indoles and Chiral Spiropyrazolones.Journal of the American Chemical Society · 2026Article
- Electrochemical Phosphorochalcogenations for the Synthesis of Phosphorochalcogenothioates.The Journal of organic chemistry · 2026Article
- Site-Selective Electrochemical Intramolecular C(spThe Journal of organic chemistry · 2025Article
- Parametrization of κACS catalysis · 2025Article
- Electrochemical Enantioselective C-H Annulation by Achiral Rhodium(III)/Chiral Brønsted Base Domino Catalysis.ACS catalysis · 2024Article
- Electrochemical cascade migratoryChemical science · 2024Article
- The crucial role of silver(I)-salts as additives in C-H activation reactions: overall analysis of their versatility and applicability.Chemical Society reviews · 2023Review
- Cobaltaelectro-Catalyzed C-H Annulation with Allenes for Atropochiral andACS catalysis · 2023Article
- Rh-Catalyzed [3+2] Annulation of Cyclic Ketimines and Alkynyl Chloride: A Strategy for Accessing Unsymmetrically Substituted and Highly Functionalizable Indenes.Organic letters · 2022Article
- Electrochemical Palladium-Catalyzed Oxidative Carbonylation-Cyclization of Enallenols.Angewandte Chemie (International ed. in English) · 2022Article
- Silver-Free C-H Activation: Strategic Approaches towards Realizing the Full Potential of C-H Activation in Sustainable Organic Synthesis.Angewandte Chemie (International ed. in English) · 2022Review
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Despite indisputable progress in the development of electrochemical transformations, electrocatalytic annulations for the synthesis of biologically relevant three-dimensional spirocyclic compounds has as of yet not been accomplished. In sharp contrast, herein, we describe the palladaelectro-catalyzed C-H activation/[3 + 2] spiroannulation of alkynes by 1-aryl-2-naphthols. Likewise, a cationic rhodium(iii) catalyst was shown to enable electrooxidative [3 + 2] spiroannulations
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