ArticlePolymers2022
Integrating Boronic Esters and Anthracene into Covalent Adaptable Networks toward Stimuli-Responsive Elastomers.
Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 14 citations in OpenAlex.
- Enhanced Fuel Cell Performance with Robust Pyridinium-Derivative-Functionalized SBS Triblock Copolymer Anion-Exchange Membranes.ACS applied materials & interfaces · 2026Article
- Structure-Property Relationships of Elastomeric Vinylogous Urethane Thermosets and Their Application as Closed-Loop Recyclable Strain Sensors.Macromolecules · 2025Article
- Dynamic Boronic Ester Cross-Linked Polymers with Tunable Properties via Side-Group Engineering.Polymers · 2024Article
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Authors and funding
6 authors at 2 institutions in 1 country.
Funding
Abstract
Stimuli-responsive polymer materials have a promising potential application in many areas. However, integrating multi-stimuli into one elastomer is still a challenge. Here, we utilized boronic esters and anthracene to prepare a cross-linked poly(styrene-butadiene-styrene) (SBS) which was endowed with responsiveness to three stimuli (light, heat, and alcohols). SBS was first functionalized with a certain amount of dihydroxyl groups via a thiol-ene "click" reaction between unsaturated double bonds in PB block and thioglycerol. Then, 9-anthraceneboronic acid was applied to form a cross-linked SBS network upon heat and ultraviolet radiation (λ = 365 nm). The prepared elastomer was demonstrated to be stimuli-responsive based on the dynamic nature of boronic esters and the reversible dimerization of anthracene. In addition, the mechanical properties of the elastomer could be regulated continuously owing to the stimulus responsiveness to ultraviolet or heat.
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Registered trials
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