ReviewAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2022
A Review of State of the Art in Phosphine Ligated Gold Clusters and Application in Catalysis.
Review in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
25 citing papers in PubMed.
- [AuSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Phosphine-Functionalized Squaramides as Responsive Organogelators: Structure, Gelation, and Metal-Ion Sensing.The Journal of organic chemistry · 2026Article
- Ligand Engineering of Dithiolate-Protected AuNano letters · 2026Article
- Mechanism governing the formation of atomically precise dithiolate-protected gold nanoclusters.Chemical science · 2026Article
- Photoluminescence of ligand-protected gold nanoclusters: progress in experimental and theoretical studies.Chemical science · 2026Review
- Hypercarbon-Centered Gold(I)-Copper(I) Clusters Exhibiting a Dissolution/Crystallization-Induced Photoluminochromism.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Photonic Nanomaterials for Wearable Health Solutions.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Structural effects of arsine ligands on C-H difunctionalization of thiophene.Chemical science · 2025Article
- Exploring Quantum Computing for Metal Cluster Analysis.The journal of physical chemistry. A · 2025Article
- AuAngewandte Chemie (International ed. in English) · 2025Article
- Molecular Gold Nanoclusters for Advanced NIR-II Bioimaging and Therapy.Chemical reviews · 2025Review
- Electrosynthesis of Atomically Precise Au Nanoclusters.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Ligand-Dependent Intracluster Interactions in Electrochemical COSmall (Weinheim an der Bergstrasse, Germany) · 2025Article
- Functional utility of gold complexes with phosphorus donor ligands in biological systems.Coordination chemistry reviews · 2025Article
- Enantioselective Assembly of Fully Substituted α-Amino Allenoates Through a Mannich Addition and Stepwise [3,3]-σ Rearrangement Sequence.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Influence of Pd, Pt and Au nanoparticles in the photocatalytic performance of N-TiOPhilosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2024Article
- Surface Functionalization of Gold Nanoparticles Using Alkyne Derivatives: Applications in Chemical Sensing.ACS applied materials & interfaces · 2024Article
- Arylgold nanoclusters: Phenyl-stabilized AuScience advances · 2024Article
- AuMolecules (Basel, Switzerland) · 2024Article
- Biological Interaction and Imaging of Ultrasmall Gold Nanoparticles.Nano-micro letters · 2023Review
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Atomically precise gold clusters are highly desirable due to their well-defined structure which allows the study of structure-property relationships. In addition, they have potential in technological applications such as nanoscale catalysis. The structural, chemical, electronic, and optical properties of ligated gold clusters are strongly defined by the metal-ligand interaction and type of ligands. This critical feature renders gold-phosphine clusters unique and distinct from other ligand-protected gold clusters. The use of multidentate phosphines enables preparation of varying core sizes and exotic structures beyond regular polyhedrons. Weak gold-phosphorous (Au-P) bonding is advantageous for ligand exchange and removal for specific applications, such as catalysis, without agglomeration. The aim of this review is to provide a unified view of gold-phosphine clusters and to present an in-depth discussion on recent advances and key developments for these clusters. This review features the unique chemistry, structural, electronic, and optical properties of gold-phosphine clusters. Advanced characterization techniques, including synchrotron-based spectroscopy, have unraveled substantial effects of Au-P interaction on the composition-, structure-, and size-dependent properties. State-of-the-art theoretical calculations that reveal insights into experimental findings are also discussed. Finally, a discussion of the application of gold-phosphine clusters in catalysis is presented.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.