Evidence map›Paper›PMID 35329681›Full record

ArticleMaterials (Basel, Switzerland)2022

Combined Electrochemical, Raman Analysis and Machine Learning Assessments of the Inhibitive Properties of an 1,3,4-Oxadiazole-2-Thiol Derivative against Carbon Steel Corrosion in HCl Solution.

Simona Varvara, Camelia Berghian-Grosan, Gianina Damian, Maria Popa, Florin Popa

Abstract read
In one paragraph

Article in Materials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Synthesis and Mechanism of a Green Scale and Corrosion Inhibitor.International journal of molecular sciences · 2024
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Simona VarvaraDepartment of Cadastre, Civil and Environmental Engineering, "1 Decembrie 1918" University of Alba Iulia, 15-17 Unirii Street, 510009 Alba Iulia, Romania.ORCID 0000-0003-2990-388X
Camelia Berghian-GrosanNational Institute for Research and Development of Isotopic and Molecular Technologies, 67-103 Donat Street, 400293 Cluj-Napoca, Romania.
Gianina DamianDepartment of Cadastre, Civil and Environmental Engineering, "1 Decembrie 1918" University of Alba Iulia, 15-17 Unirii Street, 510009 Alba Iulia, Romania.
Maria PopaDepartment of Cadastre, Civil and Environmental Engineering, "1 Decembrie 1918" University of Alba Iulia, 15-17 Unirii Street, 510009 Alba Iulia, Romania.
Florin PopaMaterials Science and Engineering Department, Technical University of Cluj-Napoca, 103-105 Muncii Avenue, 400641 Cluj-Napoca, Romania.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The inhibiting properties of 5-(4-pyridyl)-1,3,4-oxadiazole-2-thiol (PyODT) on the corrosion of carbon steel in 1.0 M HCl solution were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy, Raman spectroscopy, and SEM-EDX analysis. An approach based on machine learning algorithms and Raman data was also applied to follow the carbon steel degradation in different experimental conditions. The electrochemical measurements revealed that PyODT behaves as a mixed-type corrosion inhibitor, reaching an efficiency of about 93.1% at a concentration of 5 mM, after 1 h exposure to 1.0 M HCl solution. Due to the molecular adsorption and structural organization of PyODT molecules on the C-steel surface, higher inhibitive effectiveness of about 97% was obtained at 24 h immersion. The surface analysis showed a significantly reduced degradation state of the carbon steel surface in the presence of PyODT due to the inhibitor adsorption revealed by Raman spectroscopy and the presence of N and S atoms in the EDX spectra. The combination of Raman spectroscopy and machine learning algorithms was proved to be a facile and reliable tool for an incipient identification of the corrosion sites on a metallic surface exposed to corrosive environments.

Indexed as

1,3,4-oxadiazole derivativecarbon steelcorrosionelectrochemical impedance spectroscopymachine learning algorithmspolarization curvesRaman spectroscopySEM-EDX

Identifiers

PMID35329681
PMCPMC8950990

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.