ArticleScience advances2022
Full-nitro-nitroamino cooperative action: Climbing the energy peak of benzenes with enhanced chemical stability.
Article in Science advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- H-Bonding-Induced Repulsion Between Small Groups Toward a Highly Puckered Benzene.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Potassium-Ion-Directed Three-Dimensional Assembly of a Dense and Thermally Robust Nitrogen-Rich Tetrazine Framework.Chemistry, an Asian journal · 2026Article
- An Insensitive Energetic Material as a High-Performance Organic Cathode Toward Dual-Mode Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- A DFT study on the structures, properties, and interfacial interactions of cage-like HMX@cyclo[n]carbons energetic composites.Journal of molecular modeling · 2026Article
- Isosteric Substitution Enables Rational Design of Two-Dimensional Energetic Crystals.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Synthesis and Characterization of Polynorbornenes with Nitronaphthyl Side-Chains.Macromolecular rapid communications · 2025Article
- A Water-Based and Continuous-Flow-Usable Cascade: Sustainable Synthesis of Tetrazolo-Fused Heterocycles.JACS Au · 2025Article
- Introducing Azide into Fully Nitrated Systems: Charge Mutations toward Advanced Initiators.JACS Au · 2025Article
- Design and computational screening of high-energy, low-sensitivity bistetrazole-based energetic molecules.RSC advances · 2025Article
- Encapsulating Azolates Within Cationic Metal-Organic Frameworks for High-Energy-Density Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Boosting the Energetic Performance of Trinitromethyl-1,2,4-oxadiazole Moiety by Increasing Nitrogen-Oxygen in the Bridge.International journal of molecular sciences · 2022Article
Corrections and comments
- Erratum issued
Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
More nitro groups accord benzenes with higher energy but lower chemical stability. Hexanitrobenzene (HNB) with a fully nitrated structure has stood as the energy peak of organic explosives since 1966, but it is very unstable and even decomposes in moist air. To increase the energy limit and strike a balance between energy and chemical stability, we propose an interval full-nitro-nitroamino cooperative strategy to present a new fully nitrated benzene, 1,3,5-trinitro-2,4,6-trinitroaminobenzene (TNTNB), which was synthesized using an acylation-activation-nitration method. TNTNB exhibits a high density (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.