ArticleAngewandte Chemie (International ed. in English)2022
N-Heterocyclic Carbene Based Nanolayer for Copper Film Oxidation Mitigation.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- N-Heterocyclic carbenes on copper: a dynamic and sensitive interplay between surface functionalization and etching.Chemical science · 2026Article
- Ultra-Thin and Highly Insulating Aromatic Monolayers by N-Heterocyclic Carbenes.Angewandte Chemie (International ed. in English) · 2026Article
- Stable Synapse-Like Memory Switching in N-Heterocyclic Carbene Monolayers.Angewandte Chemie (International ed. in English) · 2026Article
- Combined electrodeposition and electropolymerization method to produce surface-bound polystyrenyl NHC thin films.Chemical science · 2026Article
- Anodic coordination polymerization for bilayer passivation of copper against oxidation.Nature communications · 2026Article
- N-Heterocyclic Carbenes on a III-V Semiconductor: From Chain Formation to Ordered Monolayers.Angewandte Chemie (International ed. in English) · 2025Article
- Article
- Heterobinuclear Molecular Precursors Direct the Formation of Supported Subnanometer Cu-M Clusters with Tunable Catalytic Behavior.ACS applied materials & interfaces · 2025Article
- A ligand oxidation structure-adaptive strategy for copper passivation.Nature communications · 2025Article
- NanoarchitecturedACS applied materials & interfaces · 2025Article
- Self-Assembled Monolayer of N-Heterocyclic Carbene as a Primer in a Dual-Layer Coating for Corrosion Protection on Iron.Angewandte Chemie (International ed. in English) · 2025Article
- An impermeable copper surface monolayer with high-temperature oxidation resistance.Nature communications · 2025Article
- In-situ electrochemical activation accelerates the magnesium-ion storage.Nature communications · 2025Article
- N-Heterocyclic Carbene Monolayers on Metal-Oxide Films: Correlations between Adsorption Mode and Surface Functionality.Langmuir : the ACS journal of surfaces and colloids · 2024Article
- One-Step Synthesis of Copper Single-Atom Nanozymes for Electrochemical Sensing Applications.Small science · 2024Article
- NHC stabilized copper nanoparticlesChemical communications (Cambridge, England) · 2023Article
- Stability of N-Heterocyclic Carbene Monolayers under Continuous Voltammetric Interrogation.ACS applied materials & interfaces · 2023Article
- Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface.Journal of the American Chemical Society · 2022Article
- N-Heterocyclic Carbene Based Nanolayer for Copper Film Oxidation Mitigation.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
5 authors.
Funding
Abstract
The wide use of copper is limited by its rapid oxidation. Main oxidation mitigation approaches involve alloying or surface passivation technologies. However, surface alloying often modifies the physical properties of copper, while surface passivation is characterized by limited thermal and chemical stability. Herein, we demonstrate an electrochemical approach for surface-anchoring of an N-heterocyclic carbene (NHC) nanolayer on a copper electrode by electro-deposition of alkyne-functionalized imidazolium cations. Water reduction reaction generated a high concentration of hydroxide ions that induced deprotonation of imidazolium cations and self-assembly of NHCs on the copper electrode. In addition, alkyne group deprotonation enabled on-surface polymerization by coupling surface-anchored and solvated NHCs, which resulted in a 2 nm thick NHC-nanolayer. Copper film coated with a NHC-nanolayer demonstrated high oxidation resistance at elevated temperatures and under alkaline conditions.
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