ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Acenaphthenoannulation Induced by the Dual Lewis Acidity of Alumina.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed, 11 citations in OpenAlex.
- Naphthalimide-Buckybowl Tweezer for Selective Recognition of Fullerene CChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Acenaphthenoannulation Induced by the Dual Lewis Acidity of Alumina.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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Authors and funding
9 authors at 3 institutions in 1 country.
Funding
Abstract
We have discovered a dual (i. e., soft and hard) Lewis acidity of alumina that enables rapid one-pot π-extension through the activation of terminal alkynes followed by C-F activation. The tandem reaction introduces an acenaphthene fragment - an essential moiety of geodesic polyarenes. This reaction provides quick access to elusive non-alternant polyarenes such as π-extended buckybowls and helicenes through three-point annulation of the 1-(2-ethynyl-6-fluorophenyl)naphthalene moiety. The versatility of the developed method was demonstrated by the synthesis of unprecedented structural fragments of elusive geodesic graphene nanoribbons.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.