ArticleJournal of the American Chemical Society2022
Self-Sorting Governed by Chelate Cooperativity.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Salt-bridged macrocycles as building blocks for aqueous supramolecular nanotube formation.Chemical science · 2026Article
- In-Situ Exploration of Phytic Acid-Mediated Supramolecular Self-Assembly and Gelation.Analytical chemistry · 2026Article
- Tailoring Tubular Supramolecular Polymers with Polar Lumens to Host Hydrophilic Dye Molecules.Angewandte Chemie (International ed. in English) · 2025Article
- Homochiral Self-Sorting During Macrocycle Formation and their Chiroptical Properties.ChemistryOpen · 2025Article
- Understanding multicomponent low molecular weight gels from gelators to networks.Journal of advanced research · 2025Review
- Programmable synthesis of organic cages with reduced symmetry.Chemical science · 2024Article
- Galactosyl BODIPY-based nanoparticles as a type-I photosensitizer for HepG2 cell targeted photodynamic therapy.RSC advances · 2024Article
- Hetero-Diels-Alder Reaction between Singlet Oxygen and Anthracene Drives Integrative Cage Self-Sorting.Journal of the American Chemical Society · 2023Article
- Stacked or Folded? Impact of Chelate Cooperativity on the Self-Assembly Pathway to Helical Nanotubes from Dinucleobase Monomers.Journal of the American Chemical Society · 2023Article
- Direct Detection of Hydrogen Bonds in Supramolecular Systems UsingJournal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Self-sorting phenomena are the basis of manifold relevant (bio)chemical processes where a set of molecules is able to interact with no interference from other sets and are ruled by a number of codes that are programmed in molecular structures. In this work, we study, the relevance of chelate cooperativity as a code for achieving high self-sorting fidelities. In particular, we establish qualitative and quantitative relationships between the cooperativity of a cyclic system and the self-sorting fidelity when combined with other molecules that share identical geometry and/or binding interactions. We demonstrate that only systems displaying sufficiently strong chelate cooperativity can achieve quantitative narcissistic self-sorting fidelities either by dictating the distribution of cyclic species in complex mixtures or by ruling the competition between the intra- and intermolecular versions of a noncovalent interaction.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.