ArticleChemical science2022
Combining metal-metal cooperativity, metal-ligand cooperativity and chemical non-innocence in diiron carbonyl complexes.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Long-range metal-metal cooperative nitrile activation in 1,8-diazaanthracene-supported dicopper complexes.Chemical communications (Cambridge, England) · 2026Article
- Solvent-temperature coupled hydride transfer controls product selectivity in the HSiRChemical science · 2026Article
- Combined Metal-Metal and Metal-Ligand Cooperativity in Dicopper-Catalyzed Azide-Alkyne Cycloaddition Reactions.Organometallics · 2025Article
- Chloride, Alkoxide, or Silicon: The Bridging Ligand Dictates the Spin State in Dicobalt Expanded Pincer Complexes.Organometallics · 2025Article
- Cyclopropanation Using Electrons Derived from Hydrogen: Reaction of Alkenes and Hydrogen without Hydrogenation.JACS Au · 2024Article
- Triiron Complex withInorganic chemistry · 2024Article
- Homotropic Cooperativity in Iron-Catalyzed Alkyne Cyclotrimerizations.ACS catalysis · 2023Article
- Diiron Aminocarbyne Complexes with NCEMolecules (Basel, Switzerland) · 2023Article
- Quantification of the Steric Properties of 1,8-Naphthyridine-Based Ligands in Dinuclear Complexes.Organometallics · 2023Article
- E-selective Semi-hydrogenation of Alkynes under Mild Conditions by a Diruthenium Hydride Complex.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- The Backbone of Success of P,N-Hybrid Ligands: Some Recent Developments.Molecules (Basel, Switzerland) · 2022Review
- Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases.Molecules (Basel, Switzerland) · 2022Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Several metalloenzymes, including [FeFe]-hydrogenase, employ cofactors wherein multiple metal atoms work together with surrounding ligands that mediate heterolytic and concerted proton-electron transfer (CPET) bond activation steps. Herein, we report a new dinucleating PNNP expanded pincer ligand, which can bind two low-valent iron atoms in close proximity to enable metal-metal cooperativity (MMC). In addition, reversible partial dearomatization of the ligand's naphthyridine core enables both heterolytic metal-ligand cooperativity (MLC) and chemical non-innocence through CPET steps. Thermochemical and computational studies show how a change in ligand binding mode can lower the bond dissociation free energy of ligand C(sp
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