ArticleGreen chemistry : an international journal and green chemistry resource : GC2022
Dehydrogenative ester synthesis from enol ethers and water with a ruthenium complex catalyzing two reactions in synergy.
Article in Green chemistry : an international journal and green chemistry resource : GC, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 15 citations in OpenAlex.
- Selective Oxygenation of 3,4-Dihydro-2H-Pyran to 5,6-Dihydro-2H-Pyran-2-One With Pd/C Catalyst and Molecular Oxygen.ChemSusChem · 2026Article
- Catalytic Oxidation of Carbon-Halogen Bonds by Water with HJournal of the American Chemical Society · 2025Article
- Direct Synthesis of Polyesterether from Ethylene Glycol.ACS sustainable chemistry & engineering · 2025Article
- Metal-Ligand Cooperation with Thiols as Transient Cooperative Ligands: Acceleration and Inhibition Effects in (De)Hydrogenation Reactions.Accounts of chemical research · 2024Article
- Selective oxidation of silanes into silanols with water using [MnBr(CO)Chemical science · 2022Article
- Oxidation of Organic Compounds Using Water as the Oxidant with HAccounts of chemical research · 2022Article
- Sustainable catalysis with fluxional acridine-based PNP pincer complexes.Chemical communications (Cambridge, England) · 2022Review
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report the dehydrogenative synthesis of esters from enol ethers using water as the formal oxidant, catalyzed by a newly developed ruthenium acridine-based PNP(Ph)-type complex. Mechanistic experiments and density functional theory (DFT) studies suggest that an inner-sphere stepwise coupled reaction pathway is operational instead of a more intuitive outer-sphere tandem hydration-dehydrogenation pathway.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.