Evidence map›Paper›PMID 35302701›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Dinitrogen Coordination to a High-Spin Diiron(I/II) Species.

Juan F Torres, Collin H Oi, Ian P Moseley, Nabila El-Sakkout, Brian J Knight, Jason Shearer, Ricardo García-Serres, Joseph M Zadrozny, Leslie J Murray

Open access · greenAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
0.6field-weighted citation impact, top 43% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 16 citations in OpenAlex.

  1. Oxidatively Induced Reductive NJournal of the American Chemical Society · 2025
    Article
  2. Article
  3. Partial Deoxygenative CO Homocoupling by a Diiron Complex.Angewandte Chemie (International ed. in English) · 2023
    Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 4 institutions in 2 countries.

Juan F TorresCenter for Catalysis and Florida Center for Heterocyclic Chemistry, Department of Chemistry, University of Florida, Gainesville, FL 32611, USA.
Collin H OiCenter for Catalysis and Florida Center for Heterocyclic Chemistry, Department of Chemistry, University of Florida, Gainesville, FL 32611, USA.
Ian P MoseleyDepartment of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.
Nabila El-SakkoutUniv. Grenoble Alpes, CNRS, CEA, IRIG, Laboratoire de Chimie et Biologie des Métaux, 17 rue des Martyrs, 38000, Grenoble, France.
Brian J KnightCenter for Catalysis and Florida Center for Heterocyclic Chemistry, Department of Chemistry, University of Florida, Gainesville, FL 32611, USA.
Jason ShearerDepartment of Chemistry, Trinity University, San Antonio, TX 78212, USA.
Ricardo García-SerresUniv. Grenoble Alpes, CNRS, CEA, IRIG, Laboratoire de Chimie et Biologie des Métaux, 17 rue des Martyrs, 38000, Grenoble, France.
Joseph M ZadroznyDepartment of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.
Leslie J MurrayCenter for Catalysis and Florida Center for Heterocyclic Chemistry, Department of Chemistry, University of Florida, Gainesville, FL 32611, USA.ORCID 0000-0002-1568-958X
University of Florida · USCentre National de la Recherche Scientifique · FRColorado State University · USTrinity University · US

Funding

Ligand effects on reactivity of hydride-decorated and reduced multi-iron compoundsR01GM123241 · NIGMS · UNIVERSITY OF FLORIDA · PI MURRAY, LESLIE JUSTIN · 2017 to 2021
$1.4M
NIGMS NIH HHS R01 GM123241
6 · The paper itself

Abstract

Dinitrogen coordination to iron centers underpins industrial and biological fixation in the Haber-Bosch process and by the FeM cofactors in the nitrogenase enzymes. The latter employ local high-spin metal centers; however, iron-dinitrogen coordination chemistry remains dominated by low-valent states, contrasting the enzyme systems. Here, we report a high-spin mixed-valent cis-(μ-1,2-dinitrogen)diiron(I/II) complex [(FeBr)

Indexed as

IronNitrogenaseIronNitrogenaseElectronic StructureMixed-Valent CompoundsMultiiron ComplexesNitrogen Fixation

Identifiers

PMID35302701
PMCPMC9117494
OpenAlexW4220887109

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.