ArticleNature materials2022
Coupling structural evolution and oxygen-redox electrochemistry in layered transition metal oxides.
Article in Nature materials, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
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- Tailoring Local Superstructure Units to Mitigate Voltage Decay in Na-Ion Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Trace Mn Doping Optimized the Electronic Structure and Improved the Rate Performance of NaSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Tailoring Surface Chemistry for Robust and Ambient-Stable Sodium Layered Oxide Cathodes.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Approaching Zero Voltage Attenuation of Lithium-Rich Cathodes through Electrochemical Relaxation.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Regulation of local chemistry in O3-type layered oxide cathodes for practical sodium-ion batteries.Chemical science · 2026Article
- Unlocking Energy Potential: Exploiting Anionic Redox Activity in Na-Based Layered Oxides.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Deciphering competing elementary steps to correlate electrocatalyst chemical state with activity.Science advances · 2026Article
- Understanding the degradation complexity of ultrahigh-energy lithium metal batteries.Nature reviews. Chemistry · 2026Review
- Boosting LiNano-micro letters · 2026Review
- Enhanced Oxygen Redox Activity and Structure Stability of P2-Type Manganese-Based Cathodes Through Medium-Entropy Strategy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Substitution and electrochemistry in layered oxide cathode materials for sodium-ion batteries.Nature reviews. Chemistry · 2026Review
- Toward Practical Li-Ion Cells With Li/Mn-Rich Layered Oxide Cathodes: A Techno-Economic Perspective on Material and Cell Design.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- FeNbAdvanced materials (Deerfield Beach, Fla.) · 2025Article
- Recovery of High-Voltage Oxygen Redox Activity by Eliminating Residual Oxygen Dimers.Journal of the American Chemical Society · 2025Article
- Lattice O-O ligands in Fe-incorporated hydroxides enhance water oxidation electrocatalysis.Nature chemistry · 2025Article
- Post-oxidation of all-organic electrocatalysts to promote O-O coupling in water oxidation.Nature communications · 2025Article
- The Effect of K-Doping on Activation in Co-Free Li-Rich Cathodes.Chemistry, an Asian journal · 2025Article
- Superstoichiometric reversible and manipulable copper-ion intercalation in niobium selenide.Nature communications · 2025Article
- Metal-to-metal charge transfer for stabilizing high-voltage redox in lithium-rich layered oxide cathodes.Science advances · 2025Article
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Authors and funding
17 authors.
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Abstract
Lattice oxygen redox offers an unexplored way to access superior electrochemical properties of transition metal oxides (TMOs) for rechargeable batteries. However, the reaction is often accompanied by unfavourable structural transformations and persistent electrochemical degradation, thereby precluding the practical application of this strategy. Here we explore the close interplay between the local structural change and oxygen electrochemistry during short- and long-term battery operation for layered TMOs. The substantially distinct evolution of the oxygen-redox activity and reversibility are demonstrated to stem from the different cation-migration mechanisms during the dynamic de/intercalation process. We show that the π stabilization on the oxygen oxidation initially aids in the reversibility of the oxygen redox and is predominant in the absence of cation migrations; however, the π-interacting oxygen is gradually replaced by σ-interacting oxygen that triggers the formation of O-O dimers and structural destabilization as cycling progresses. More importantly, it is revealed that the distinct cation-migration paths available in the layered TMOs govern the conversion kinetics from π to σ interactions. These findings constitute a step forward in unravelling the correlation between the local structural evolution and the reversibility of oxygen electrochemistry and provide guidance for further development of oxygen-redox layered electrode materials.
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