ArticleNature communications2022
Two-dimensional covalent organic framework films prepared on various substrates through vapor induced conversion.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed, 129 citations in OpenAlex.
- Solid-vapor synthesis of dynamic crystalline one-dimensional supramolecular polymers from amorphous macrocycles.Nature communications · 2026Article
- Humidity-Guided In Situ Polymerization for Controlled Formation of Smooth, Oriented Covalent Organic Framework Films.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Wet Transfer of In Situ Grown Azo-Containing Two-Dimensional Conjugated Covalent Organic Framework Films for Photoswitchable Electronic Devices.Angewandte Chemie (International ed. in English) · 2026Article
- Molecular bridge engineering in covalent organic frameworks for enhanced electronic transport.Nature communications · 2026Article
- SMAIS: a universal platform for the on-water surface synthesis of two-dimensional polymer crystals.Nature protocols · 2026Review
- Ambient one-step synthesis and direct coating of highly crystalline covalent organic frameworks on arbitrary surfaces.Science advances · 2026Article
- Towards single-crystalline two-dimensional poly(arylene vinylene) covalent organic frameworks.Nature chemistry · 2026Article
- Sustained hydrogen peroxide production via MXene-functionalized supramolecular docking.Nature communications · 2026Article
- Weak localized electrons enhance electronic coherence for efficient photocatalytic uranium removal from nuclear wastewater.Nature communications · 2026Article
- Constructing out-of-plane oriented two-dimensional covalent organic framework films for stretchable electronics.Nature communications · 2025Article
- Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Asymmetric ionic covalent organic framework membranes with tunable Turing patterns prepared via ion regulated strategy.Nature communications · 2025Article
- Patterning and Dynamics of Structured Surfaces in Metal/Covalent Organic Frameworks and Polymer Chemistry.Topics in current chemistry (Cham) · 2025Review
- Structure Directing Acid-Amine Salt Films for Imine-Linked Covalent Organic Framework Films by Chemical Vapor Deposition.Journal of the American Chemical Society · 2025Article
- Moiré two-dimensional covalent organic framework superlattices.Nature chemistry · 2025Article
- Continuous In-Situ Polymerization of Complex-Based Films for High-Performance Electrochromic Devices.Molecules (Basel, Switzerland) · 2025Article
- High-performance 2D electronic devices enabled by strong and tough two-dimensional polymer with ultra-low dielectric constant.Nature communications · 2024Article
- Diffusion limited synthesis of wafer-scale covalent organic framework films for adaptative visual device.Nature communications · 2024Article
- Photochemical and Patternable Synthesis of 2D Covalent Organic Framework Thin Film Using Dynamic Liquid/Solid Interface.Small methods · 2024Article
- Self-assembled dipeptide confined in covalent organic polymers for fluorescence sensing of tryptamine in fermented meat products.Mikrochimica acta · 2024Article
Corrections and comments
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Authors and funding
12 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Covalent organic frameworks (COFs) can exhibit high specific surface area and catalytic activity, but traditional solution-based synthesis methods often lead to insoluble and infusible powders or fragile films on solution surface. Herein we report large-area -C=N- linked two-dimensional (2D) COF films with controllable thicknesses via vapor induced conversion in a chemical vapor deposition (CVD) system. The assembly process is achieved by reversible Schiff base polycondensation between PyTTA film and TPA vapor, which results in a uniform organic framework film directly on growth substrate, and is driven by π-π stacking interactions with the aid of water and acetic acid. Wafer-scale 2D COF films with different structures have been successfully synthesized by adjusting their building blocks, suggesting its generic applicability. The carrier mobility of PyTTA-TPA COF films can reach 1.89 × 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.