Evidence map›Paper›PMID 35299818›Full record

ArticleThe journal of physical chemistry. C, Nanomaterials and interfaces2022

BN-Substitution in Dithienylpyrenes Prevents Excimer Formation in Solution and in the Solid State.

Yannik Appiarius, Philipp J Gliese, Stephan A W Segler, Pascal Rusch, Jiangbin Zhang, Paul J Gates, Rumpa Pal, Lorraine A Malaspina, Kunihisa Sugimoto, Tim Neudecker and 4 more

Open access · greenAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in The journal of physical chemistry. C, Nanomaterials and interfaces, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.8field-weighted citation impact, top 33% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 13 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors at 7 institutions in 6 countries.

Yannik AppiariusInstitute for Analytical and Organic Chemistry, University of Bremen, Leobener Straße 7, D-28359 Bremen, Germany.ORCID https://orcid.org/0000-0002-9849-6950
Philipp J GlieseInstitute for Analytical and Organic Chemistry, University of Bremen, Leobener Straße 7, D-28359 Bremen, Germany.
Stephan A W SeglerInstitute for Analytical and Organic Chemistry, University of Bremen, Leobener Straße 7, D-28359 Bremen, Germany.
Pascal RuschInstitute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstraße 3a, D-30167 Hannover, Germany.
Jiangbin ZhangCollege of Advanced Interdisciplinary Studies, National University of Defense Technology, 410073 Changsha, Hunan, China.
Paul J GatesSchool of Chemistry, University of Bristol, Cantock's Close, BS8 1TS Bristol, U.K.ORCID https://orcid.org/0000-0001-8619-7745
Rumpa PalInstitute of Inorganic Chemistry and Crystallography, University of Bremen, Leobener Straße 7, D-28359 Bremen, Germany.
Lorraine A MalaspinaDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.
Kunihisa SugimotoJapan Synchrotron Radiation Research Institute (JASRI), 1-1-1, Kouto, Sayo-cho, Hyogo 679-5198, Japan.
Tim NeudeckerInstitute for Physical and Theoretical Chemistry, University of Bremen, Leobener Straße 7, D-28359 Bremen, Germany.ORCID https://orcid.org/0000-0001-7599-3578
Nadja C BigallInstitute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstraße 3a, D-30167 Hannover, Germany.ORCID https://orcid.org/0000-0003-0171-1106
Simon GrabowskyDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.ORCID https://orcid.org/0000-0002-3377-9474
Artem A BakulinDepartment of Chemistry, Imperial College London, Imperial College Rd, SW7 2AZ London, U.K.ORCID https://orcid.org/0000-0002-3998-2000
Anne StaubitzInstitute for Analytical and Organic Chemistry, University of Bremen, Leobener Straße 7, D-28359 Bremen, Germany.ORCID https://orcid.org/0000-0002-9040-3297
University of Bremen · DELeibniz University Hannover · DEUniversity of Bern · CHJapan Synchrotron Radiation Research Institute · JPNational University of Defense Technology · CNUniversity of Bristol · GBUniversity of Cambridge · GB

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Boron-nitrogen substitutions in polycyclic aromatic hydrocarbons (PAHs) have a strong impact on the optical properties of the molecules due to a significantly more heterogeneous electron distribution. However, besides these single-molecule properties, the observed optical properties of PAHs critically depend on the degree of intermolecular interactions such as π-π-stacking, dipolar interactions, or the formation of dimers in the excited state. Pyrene is the most prominent example showing the latter as it exhibits a broadened and strongly bathochromically shifted emission band at high concentrations in solution compared to the respective monomers. In the solid state, the impact of intermolecular interactions is even higher as it determines the crystal packing crucially. In this work, a thiophene-flanked BN-pyrene (

Identifiers

PMID35299818
PMCPMC8919264
OpenAlexW4220779151

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.