ArticleAngewandte Chemie (International ed. in English)2022
Organic Four-Electron Redox Systems Based on Bipyridine and Phenanthroline Carbene Architectures.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
7 citing papers in PubMed, 54 citations in OpenAlex.
- Feedstock-Derived Thiophene Radical Anions Exhibiting Redox Stability at Extreme Potentials.Angewandte Chemie (International ed. in English) · 2025Article
- Isolation of Elusive Fluoflavine Radicals in Two Differing Oxidation States.Journal of the American Chemical Society · 2024Article
- Review
- On-demand engineerable visible spectrum by fine control of electrochemical reactions.National science review · 2024Article
- A bis-NHC-CAAC dimer derived dicationic diradical.Chemical science · 2022Article
- Gauging Radical Stabilization with Carbenes.Angewandte Chemie (International ed. in English) · 2022Article
- Organic Four-Electron Redox Systems Based on Bipyridine and Phenanthroline Carbene Architectures.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
3 authors at 2 institutions in 1 country.
Funding
Abstract
Novel organic redox systems that display multistage redox behaviour are highly sought-after for a series of applications such as organic batteries or electrochromic materials. Here we describe a simple strategy to transfer well-known two-electron redox active bipyridine and phenanthroline architectures into novel strongly reducing four-electron redox systems featuring fully reversible redox events with up to five stable oxidation states. We give spectroscopic and structural insight into the changes involved in the redox-events and present characterization data on all isolated oxidation states. The redox-systems feature strong UV/Vis/NIR polyelectrochromic properties such as distinct strong NIR absorptions in the mixed valence states. Two-electron charge-discharge cycling studies indicate high electrochemical stability at strongly negative potentials, rendering the new redox architectures promising lead structures for multi-electron anolyte materials.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.