ArticleNature communications2022
Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 30 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
30 citing papers in PubMed.
- All-Dry Molecular Scale Processing for Shaping Open Pockets with COChem & bio engineering · 2026Article
- Single Crystals of Perylene Diimide-Based Two-Dimensional Covalent Organic Frameworks.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Ambient one-step synthesis and direct coating of highly crystalline covalent organic frameworks on arbitrary surfaces.Science advances · 2026Article
- Towards single-crystalline two-dimensional poly(arylene vinylene) covalent organic frameworks.Nature chemistry · 2026Article
- Mechanistic Insights into Layered Growth of Imine-Linked Bilayer 2D Covalent Organic Frameworks.Journal of the American Chemical Society · 2026Article
- Single-Crystalline Borate Covalent Organic Frameworks for Solid-State Lithium Metal Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Weak localized electrons enhance electronic coherence for efficient photocatalytic uranium removal from nuclear wastewater.Nature communications · 2026Article
- Single-crystal 2D covalent organic frameworks for high-capacity methane storage.Nature communications · 2026Article
- Radial growth of twist-stacked covalent organic framework nanofibers.Nature communications · 2025Article
- Dual-regulated covalent organic framework membranes with near-theoretical pore sizes for angstrom-scale ion separations.Science advances · 2025Article
- MitoSiege-Driven Catalase Collapse: A GSH-Responsive, Mitochondria-Targeted COF Prodrug for Amplified Chemodynamic Therapy.Angewandte Chemie (International ed. in English) · 2025Article
- Article
- Unconventional Fast Room Temperature Synthesis of Covalent Organic Framework Single Crystals Unveiling Precise Structural Insights.Angewandte Chemie (International ed. in English) · 2025Article
- Toward Continuous, Oriented Covalent Organic Framework Membranes for Precise Molecular Separations.ACS nano · 2025Review
- Moiré two-dimensional covalent organic framework superlattices.Nature chemistry · 2025Article
- Synthesis of high quality two dimensional covalent organic frameworks through a self-sacrificing guest strategy.Nature communications · 2025Article
- Controlling crystallization in covalent organic frameworks to facilitate photocatalytic hydrogen production.Nature communications · 2025Article
- From Fundamentals to Synthesis: Covalent Organic Frameworks as Promising Materials for COTopics in current chemistry (Cham) · 2025Review
- Article
- Dimensionality and Molecular Packing Control of Covalent Organic Frameworks through Pendant Group Design.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
Resolving single-crystal structures of two-dimensional covalent organic frameworks (2D COFs) is a great challenge, hindered in part by limited strategies for growing high-quality crystals. A better understanding of the growth mechanism facilitates development of methods to grow high-quality 2D COF single crystals. Here, we take a different perspective to explore the 2D COF growth process by tracing growth intermediates. We discover two different growth mechanisms, nucleation and self-healing, in which self-assembly and pre-arrangement of monomers and oligomers are important factors for obtaining highly crystalline 2D COFs. These findings enable us to grow micron-sized 2D single crystalline COF Py-1P. The crystal structure of Py-1P is successfully characterized by three-dimensional electron diffraction (3DED), which confirms that Py-1P does, in part, adopt the widely predicted AA stacking structure. In addition, we find the majority of Py-1P crystals (>90%) have a previously unknown structure, containing 6 stacking layers within one unit cell.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.