Evidence map›Paper›PMID 35294095›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Sustainable Thioetherification via Electron Donor-Acceptor Photoactivation Using Thianthrenium Salts.

María Jesús Cabrera-Afonso, Albert Granados, Gary A Molander

Open access · greenAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.

0numbers the graph read from it
0cells of the map it votes in
24citing papers in PubMed
18.6field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

24 citing papers in PubMed, 181 citations in OpenAlex.

  1. C─S Bond Formation of Aryl Germanes.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Article
  3. Multicomponent Photochemical Assembly of C(spACS organic & inorganic Au · 2026
    Article
  4. Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross-Coupling.Angewandte Chemie (International ed. in English) · 2026
    Article
  5. Late-Stage Phenylation From [Chemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  6. Thianthrenium Salts in Photochemistry.Accounts of chemical research · 2026
    Article
  7. Article
  8. Article
  9. Visible-Light-Mediated Synthesis of AnomericMolecules (Basel, Switzerland) · 2025
    Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Review
  15. Article
  16. Article
  17. Difluoroalkylation of Anilines via Photoinduced Methods.The Journal of organic chemistry · 2023
    Article
  18. Article
  19. Article
  20. Sulfonium Salts as Acceptors in Electron Donor-Acceptor Complexes.Angewandte Chemie (International ed. in English) · 2023
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 2 institutions in 1 country.

María Jesús Cabrera-AfonsoDepartment of Chemistry, University of Pennsylvania, Roy and Diana Vagelos Laboratories, 231 S. 34th Street, Philadelphia, PA 19104-6323, USA.ORCID 0000-0002-3736-3206
Albert GranadosDepartment of Chemistry, University of Pennsylvania, Roy and Diana Vagelos Laboratories, 231 S. 34th Street, Philadelphia, PA 19104-6323, USA.ORCID 0000-0002-5362-5966
Gary A MolanderDepartment of Chemistry, University of Pennsylvania, Roy and Diana Vagelos Laboratories, 231 S. 34th Street, Philadelphia, PA 19104-6323, USA.ORCID 0000-0002-9114-5584
Health First · USUniversity of Pennsylvania · US

Funding

Accessing New Chemical Space via Organic SynthesisR35GM131680 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI MOLANDER, GARY A · 2019 to 2022
$2.4M
Computational Methods for Selective CatalysisR01GM087605 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI KOZLOWSKI, MARISA C · 2010 to 2019
$2.4M
Targeting Nucleic Acid Junctions with Small MoleculesR01GM118510 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI CHENOWETH, DAVID MICHAEL · 2016 to 2020
$1.6M
NIGMS NIH HHS R01 GM087605NIGMS NIH HHS R01 GM118510NIGMS NIH HHS R35 GM131680
6 · The paper itself

Abstract

The synthesis of sulfides has been widely studied because this functional subunit is prevalent in biomolecules and pharmaceuticals, as well as being a useful synthetic platform for further elaboration. Thus, various methods to build C-S bonds have been developed, but typically they require the use of precious metals or harsh conditions. Electron donor-acceptor (EDA) complex photoactivation strategies have emerged as versatile and sustainable ways to achieve C-S bond formation, avoiding challenges associated with previous methods. This work describes an open-to-air, photoinduced, site-selective C-H thioetherification from readily available reagents via EDA complex formation that tolerates a wide range of different functional groups. Moreover, C(sp

Indexed as

ElectronsSaltsHalogensMetalsOxidantsHalogensMetalsOxidantsSaltsC−S CouplingElectron Donor-Acceptor ComplexPhotochemistryThianthrenium SaltsThioethers

Identifiers

PMID35294095
PMCPMC9117462
OpenAlexW4221005462

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.