Evidence map›Paper›PMID 35289046›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Isolation of Stable Borepin Radicals and Anions.

Kimberly K Hollister, Wenlong Yang, Ranajit Mondol, Kelsie E Wentz, Andrew Molino, Aishvaryadeep Kaur, Diane A Dickie, Gernot Frenking, Sudip Pan, David J D Wilson and 1 more

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
3.2field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 32 citations in OpenAlex.

  1. One-Electron Boron-Carbon Triel Bonding.Journal of the American Chemical Society · 2025
    Article
  2. Article
  3. Article
  4. Gauging Radical Stabilization with Carbenes.Angewandte Chemie (International ed. in English) · 2022
    Article
  5. Isolation of Stable Borepin Radicals and Anions.Angewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 3 institutions in 3 countries.

Kimberly K HollisterDepartment of Chemistry, University of Virginia, 409 McCormick Rd./PO Box 400319, Charlottesville, VA 22904, USA.ORCID http://orcid.org/0000-0001-9024-4436
Wenlong YangDepartment of Chemistry, University of Virginia, 409 McCormick Rd./PO Box 400319, Charlottesville, VA 22904, USA.ORCID http://orcid.org/0000-0002-9017-7728
Ranajit MondolDepartment of Chemistry, University of Virginia, 409 McCormick Rd./PO Box 400319, Charlottesville, VA 22904, USA.ORCID http://orcid.org/0000-0001-6691-7522
Kelsie E WentzDepartment of Chemistry, University of Virginia, 409 McCormick Rd./PO Box 400319, Charlottesville, VA 22904, USA.ORCID http://orcid.org/0000-0002-0464-8010
Andrew MolinoDepartment of Chemistry and Physics, La Trobe Institute for Molecular Science, Latrobe University, Melbourne, 3086, Victoria, Australia.ORCID http://orcid.org/0000-0002-0954-9054
Aishvaryadeep KaurDepartment of Chemistry and Physics, La Trobe Institute for Molecular Science, Latrobe University, Melbourne, 3086, Victoria, Australia.
Diane A DickieDepartment of Chemistry, University of Virginia, 409 McCormick Rd./PO Box 400319, Charlottesville, VA 22904, USA.ORCID http://orcid.org/0000-0003-0939-3309
Gernot FrenkingFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, 35043, Marburg, Germany.ORCID http://orcid.org/0000-0003-1689-1197
Sudip PanFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, 35043, Marburg, Germany.ORCID http://orcid.org/0000-0003-3172-926X
David J D WilsonDepartment of Chemistry and Physics, La Trobe Institute for Molecular Science, Latrobe University, Melbourne, 3086, Victoria, Australia.ORCID http://orcid.org/0000-0002-0007-4486
Robert J GilliardDepartment of Chemistry, University of Virginia, 409 McCormick Rd./PO Box 400319, Charlottesville, VA 22904, USA.ORCID http://orcid.org/0000-0002-8830-1064
McCormick (United States) · USLa Trobe University · AUPhilipps University of Marburg · DE

Funding

German Research FoundationNational Science Foundation CHE2046544 and CHE2018870
6 · The paper itself

Abstract

Borepin, a 7-membered boron-containing heterocycle, has become an emerging molecular platform for the development of new materials and optoelectronics. While electron-deficient borepins are well-established, reduced electron-rich species have remained elusive. Herein we report the first isolable, crystalline borepin radical (2 a, 2 b) and anion (3 a, 3 b) complexes, which have been synthesized by potassium graphite (KC

Indexed as

AnionsBorepinBoronCarbenesRadicals

Identifiers

PMID35289046
PMCPMC9324096
OpenAlexW4221071451

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.